New 2D coordination polymer of cobalt(II) pivalate with 1,4-diaminobutane: synthesis and thermal properties

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Abstract

The reaction of cobalt(II) trimethyl acetate (pivalate) [Co(Рiv)2]n (HРiv = HO2CCMe3) with 1,4-diaminobutane (Dab) in absolute acetonitrile gave a 2D-coordination polymer [Co(Piv)2(Dab)2]n (I) with an admixture of the co-product, but the addition of one equivalent of 2,2´-bipyridine to the reaction mixture made it possible to isolate a single-phase sample of I (according to X-ray diffraction data) with a yield of 78%. The crystal structure of I was determined by X-ray diffraction (CCDC No. 2404406): cobalt(II) atoms in a distorted octahedral environment (CoN4O2) of two monodentate carboxylate groups and four bridging Dab molecules form a layered coordination polymer with a honeycomb-like hcb topology. The thermal behavior of I was studied by synchronous thermal analysis: thermal decomposition leads to the formation of the organic salt (H2Dab)(Piv)2, cobalt(II) pivalate, and the octanuclear complex [Co8O2(Piv)12] — the products were identified by XRD and NMR spectroscopy.

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About the authors

V. A. Bushuev

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Higher School of Economics, National Research University

Email: yambulatov@yandex.ru
Russian Federation, Moscow; Moscow

D. S. Yambulatov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Russian Federation, Moscow

N. V. Gogoleva

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Russian Federation, Moscow

F. M. Dolgushin

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: yambulatov@yandex.ru
Russian Federation, Moscow

I. V. Skabitsky

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Russian Federation, Moscow

S. S. Shapovalov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Russian Federation, Moscow

S. A. Nikolaevskii

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Russian Federation, Moscow

M. A. Kiskin

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Russian Federation, Moscow

I. L. Eremenko

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Russian Federation, Moscow

References

  1. Morritt G.H., Michaels H., Freitag M. // Chem. Phys. Rev. 2022. V. 3. Р. 011306.
  2. Xiao X., Chen Z., Varley R.J., Li C. // Smart Molecules. 2024. V. 2. Р. E20230028.
  3. Yin X., Chen X., Sun W. et al. // Energy Storage Mater. 2020.V. 25. P.846.
  4. Maiti A., Maity D.K., Halder A., Ghoshal D. // Inorg Chem. 2023. V. 62. P. 12403.
  5. Dybtsev D.N., Sapianik A.A., Fedin V.P. // Mendeleev Commun. 2017. V. 27. P. 321.
  6. Aromí G., Batsanov A.S., Christian P. et al. // Chem. Eur. J. 2003. V. 9. P.5142.
  7. Fursova E., Kuznetsova O., Ovcharenko V. et al. // Polyhedron 2007. V. 26. P.2079.
  8. Golubnichaya M.A., Sidorov A.A., Fomina I.G. et al. // Russ. Chem. Bull. 1999. V. 48. P. 1751.
  9. Bykov M., Emelina A., Kiskin M. et al. // Polyhedron. 2009. V. 28. P. 3628.
  10. Zorina‐Tikhonova E.N., Gogoleva N.V., Sidorov A.A. et al. // Eur. J. Inorg. Chem. 2017. V. 2017. P.1396.
  11. Fomina I.G., Aleksandrov G.G., Dobrokhotova Zh.V. et al. // Russ. Chem. Bull. 2006. V. 55. P. 1909.
  12. Shao D., Moorthy S., Yang X. et al. // Dalton Trans. 2022. V. 51. P. 695.
  13. Wang J., Chen N.-N., Zhang C. et al. // CrystEngComm. 2020. V. 22. P. 811.
  14. Sen A., Sato T., Ohno A. // JACS Au. 2021. V. 1. P. 2080.
  15. Zhang H., Liu G., Shi L. et al. // Nano Energy. 2016. V. 22. P. 149.
  16. Sanchis-Gual R., Coronado-Puchau M., Mallah T., Coronado E. // Coord. Chem. Rev. 2023. V. 480. P. 215025.
  17. Peng Y., Liu X.-L., Xu Z. et al. // Sep. Purif. Technol. 2025. V. 353. P. 128360.
  18. Yao W., Yang R., Xu B. et al. // Transition Met. Chem. 2024. V. 49. P. 331.
  19. Bikash Baruah J. // Coord. Chem. Rev. 2022. V. 470. P. 214694.
  20. Lian Y., Yang W., Zhang C. et al. // Ang. Chem. Intern. Ed. 2020. V. 59. P. 286.
  21. Zorina-Tikhonova E.N., Matyukhina A.K., Chistyakov A.S. // New J. Chem. 2022. V. 46. P. 21245.
  22. Chernomorova M.A., Myakinina M.S., Zhinzhilo V.A., Uflyand I.E. // Polymers (Basel). 2023. V. 15. P. 548.
  23. Roose P., Eller K., Henkes E. et al. // Ullmann’s Encyclopedia of Industrial Chemistry. Wiley, 2015. p. 1
  24. Koning C., Teuwen L., Lacave-Goffin B., Mercier J.P. // Polymer. 2001. V. 42. P. 7247.
  25. Jasinska L., Villani M., Wu J. et al. // Macromolecules. 2011. V. 44. P. 3458.
  26. Gaymans R.J., Van Utteren T.E.C., Van Den Berg J.W.A., Schuyer J. // J. Polym. Sci., Polym. Chem. Ed. 1977. V. 15. P. 537.
  27. Elsaidi S.K., Mohamed M.H., Banerjee D., Thallapally P.K. // Coord. Chem. Rev. 2018. V. 358. P. 125.
  28. Sato O. // Nature. 2016. V. 8. P. 644.
  29. Sato O., Tao J., Zhang Y.Z. // Ang. Chem. Intern. Ed. 2007. V. 46. P. 2152.
  30. Pinkowicz D., Podgajny R., Sieklucka B. // Molecular Magnetic Materials: Concepts and Applications. Wiley, 2016. P. 279.
  31. Polunin R.A., Kolotilov S. V, Kiskin M.A. et al. // Eur. J. Inorg. Chem. 2011. V. 2011. P. 4985.
  32. Minkin V.I. // Russ. Chem. Bull. 2008. V. 57. P. 687.
  33. Yambulatov D.S., Voronina J.K., Goloveshkin A.S. et al. // Int. J. Mol. Sci. 2022. V. 24. P. 215.
  34. Yeşilel O.Z., Karamahmut B., Semerci F. et al. // J. Solid. State. Chem. 2017. V. 249. P. 174.
  35. Li Y., Jiang Q., Cheng K. et al. // Z. Anorg. Allg. Chem. 2009. V.635. P. 2572.
  36. You Z.-L., Zhu H.-L., Liu W.-S. // Acta Crystallogr. C. 2004.V. 60. P. m231.
  37. Bushuev V.A., Gogoleva N.V., Nikolaevskii S.A. et al. // Molecules. 2024. V. 29. P. 2125.
  38. Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. P. 3.
  39. Sheldrick G.M. // Acta Crystallogr. C. 2015, V. 71. P. 3.
  40. Scarlett N.V.Y., Madsen I.C. // Powder Diffr. 2006. V. 21. P. 278.
  41. Nikolaevskii S.A., Petrov P.A., Sukhikh T.S. et al. // Inorg. Chim. Acta. 2020. V. 508. P. 119643.
  42. Hayashi Y., Santoro S., Azuma Y. et al. // J. Am. Chem. Soc. 2013. V. 135. P. 6192.
  43. Colthup N.B., Daly L.H., Widerley S.E. Introduction to Infrared and Raman Spectroscopy, Elsevier, 1975.
  44. Stewart J.E. // J. Chem. Phys. 1959.V. 30. P. 1259.
  45. Zeleňák V., Vargová Z., Györyová K. // Spectrochim, Acta. A. 2007. V. 66. P. 262.
  46. Max J.J., Chapados C. // J. Phys. Chem. A. 2004. V. 108. P. 3324.
  47. Strukl J.S., Walter J.L. // Spectrochim Acta. A. 1971. V. 27. P. 209.
  48. Castellucci E., Angeloni L., Neto N., Sbrana G. // Chem. Phys. 1979. V. 43. P. 365.
  49. Lutsenko I.A., Kiskin M.A., Nelyubina Y. V. // Polyhedron. 2020. V. 190. P. 114764.
  50. Singh G., Singh C.P., Mannan S.M. // J. Hazard. Mater. 2005. V. 122. P. 111.
  51. Sidorov A.A., Fomina I.G., Ponina M.O. // Russ. Chem. Bull. 2000. V. 49. P. 958.

Supplementary files

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2. Fig. 1. Fragment of the layer packing (methyl groups are not shown, the dotted lines indicate H-bonds) (a) and visualization of the topological structure of hcb in the layer (carboxylate groups and hydrogen atoms are not shown) (b) of coordination polymer I.

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3. Fig. 2. TGA (a) and DTA (b) curves for I.

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4. Scheme 1. Synthesis of compound I.

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5. Application
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