New 2D coordination polymer of cobalt(II) pivalate with 1,4-diaminobutane: synthesis and thermal properties

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Аннотация

The reaction of cobalt(II) trimethyl acetate (pivalate) [Co(Рiv)2]n (HРiv = HO2CCMe3) with 1,4-diaminobutane (Dab) in absolute acetonitrile gave a 2D-coordination polymer [Co(Piv)2(Dab)2]n (I) with an admixture of the co-product, but the addition of one equivalent of 2,2´-bipyridine to the reaction mixture made it possible to isolate a single-phase sample of I (according to X-ray diffraction data) with a yield of 78%. The crystal structure of I was determined by X-ray diffraction (CCDC No. 2404406): cobalt(II) atoms in a distorted octahedral environment (CoN4O2) of two monodentate carboxylate groups and four bridging Dab molecules form a layered coordination polymer with a honeycomb-like hcb topology. The thermal behavior of I was studied by synchronous thermal analysis: thermal decomposition leads to the formation of the organic salt (H2Dab)(Piv)2, cobalt(II) pivalate, and the octanuclear complex [Co8O2(Piv)12] — the products were identified by XRD and NMR spectroscopy.

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Авторлар туралы

V. Bushuev

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Higher School of Economics, National Research University

Email: yambulatov@yandex.ru
Ресей, Moscow; Moscow

D. Yambulatov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Ресей, Moscow

N. Gogoleva

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Ресей, Moscow

F. Dolgushin

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: yambulatov@yandex.ru
Ресей, Moscow

I. Skabitsky

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Ресей, Moscow

S. Shapovalov

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Ресей, Moscow

S. Nikolaevskii

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Ресей, Moscow

M. Kiskin

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Ресей, Moscow

I. Eremenko

N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: yambulatov@yandex.ru
Ресей, Moscow

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1. JATS XML
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2. Fig. 1. Fragment of the layer packing (methyl groups are not shown, the dotted lines indicate H-bonds) (a) and visualization of the topological structure of hcb in the layer (carboxylate groups and hydrogen atoms are not shown) (b) of coordination polymer I.

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3. Fig. 2. TGA (a) and DTA (b) curves for I.

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4. Scheme 1. Synthesis of compound I.

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5. Application
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