Activation of the polylactic acid surface by the glow discharge low-temperature plasma in Ar/air gas mixture flows with the addition of diethylamine vapor

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Abstract

The surface physicochemical properties of the polylactic acid modified by flows of low-temperature glow discharge plasma were studied. A mixture of argon and air acted as the plasma-forming gas; diethylamine vapor was injected into the plasma as a precursor of amino groups. The elemental composition and chemical state of the surface were studied using X-ray photoelectron spectroscopy. The attachment of nitrogen atoms to the polylactic acid surface and the formation of a bond between the surface carbon and the penetrated nitrogen have been established. It was shown that the hydrophilicity of the plasma modified polylactic acid surface was significantly increased. The obtained polylactic acid-based materials with the argon/air/diethylamine plasma modified surface may have prospects for use in biomedicine due to improved hydrophilicity and the presence of reactive oxygen- and nitrogen-containing functional groups on the surface.

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About the authors

А. G. Korzhova

National Research Tomsk State University

Author for correspondence.
Email: olesyalaput@gmail.com
Russian Federation, Tomsk

А. А. Bryuzgina

National Research Tomsk State University

Email: olesyalaput@gmail.com
Russian Federation, Tomsk

U. V. Khomutova

National Research Tomsk State University

Email: olesyalaput@gmail.com
Russian Federation, Tomsk

О. А. Laput

National Research Tomsk State University

Email: olesyalaput@gmail.com
Russian Federation, Tomsk

I. V. Vasenina

P.N. Lebedev Physical Institute

Email: olesyalaput@gmail.com
Russian Federation, Moscow

D. А. Zuza

Institute of High Current Electronics

Email: olesyalaput@gmail.com
Russian Federation, Tomsk

S. G. Tuyakova

National Research Tomsk State University

Email: olesyalaput@gmail.com
Russian Federation, Tomsk

I. А. Kurzina

National Research Tomsk State University

Email: olesyalaput@gmail.com
Russian Federation, Tomsk

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Supplementary files

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2. Fig. 1. Survey spectra of the polylactide surface before (1) and after modification with Ar/air (2) and Ar/air/DEA (3) plasma.

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3. Fig. 2. Regions of high-resolution C1s photoelectron spectra for PLA samples before (a) and after modification with Ar/air (b) and Ar/air/DEA (c) plasma.

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4. Fig. 3. Regions of high-resolution photoelectron spectra of N1s for samples after plasma modification Ar/air (1) and Ar/air/DEA (2).

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5. Fig. 4. SEM images of the sample surface and diagrams of the distribution of fiber diameters (in the insets) of PL (a) and PL modified with Ar/air plasma (b) and Ar/air/DEA (c).

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