Investigation of Marangoni convection during contactless crystal growth in microgravity conditions

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Abstract

The influence of melt meniscus length on the velocity caused by Marangoni convection during non-contact crystal growing has been studied by using Te-doped GaSb single crystal grown under microgravity conditions.

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About the authors

А. E. Voloshin

National Research Centre “Kurchatov Institute”; Mendeleev Russian University of Chemical Technology; National University of Science and Technology “MISIS”

Author for correspondence.
Email: voloshin@crys.ras.ru

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics

Russian Federation, Moscow; Moscow; Moscow

Е. B. Rudneva

National Research Centre “Kurchatov Institute”

Email: voloshin@crys.ras.ru

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics

Russian Federation, Moscow

V. L. Manomenova

National Research Centre “Kurchatov Institute”

Email: voloshin@crys.ras.ru

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics

Russian Federation, Moscow

А. I. Prostomolotov

Ishlinsky Institute for Problems in Mechanics of Russian Academy of Sciences

Email: voloshin@crys.ras.ru
Russian Federation, Moscow

N. А. Verezub

Ishlinsky Institute for Problems in Mechanics of Russian Academy of Sciences

Email: voloshin@crys.ras.ru
Russian Federation, Moscow

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2. Fig. 1. Crystallization regions of the rounded front (A) and face (B).

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3. Fig. 2. Averaged parallel to the crystallization front, the distribution of Te in the region of the growth of the rounded front and the calculation using the BPS model. The upper part of the figure shows a graph of the change in the gap δl between the ampoule wall and the left side of the crystal with a shift of 0.5 mm (see the text for explanations).

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4. Fig. 3. Geometry of interphase boundaries near the crystallization front in the absence of contact between the crystal and the container walls.

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5. Fig. 4. Dependence on δl, calculated from the measured values ​​of CTe, and its approximation using formula (9).

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6. Fig. 5. Schematic diagram illustrating the model for the numerical solution of a two-dimensional convective diffusion problem.

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7. Fig. 6. Schematic diagram illustrating the model for numerical calculation of the Marangoni convection velocity.

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8. Fig. 7. Results of 2D modeling of Marangoni convection: a – dependence of the maximum convective flow velocity V∞ on the gap δl between the lateral surface of the crystal and the container wall; b – distribution of the convective flow velocity; c – temperature distribution at δl = 0.05 cm.

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