Substitution in the Structure of Hydroxyapatite Doped by Iron Cations at Mechanochemical Synthesis

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Abstract

Hydroxyapatite, a mineral of the apatite group, has an important and useful property – the propensity for various kinds of substitutions, which allows to modify its properties and expand the possibilities of using the synthetic material. The properties of the synthesised substance depend on the way it is produced, as the synthesis conditions influence the structural and morphological characteristics of the particles being formed. This paper shows that at mechanochemical synthesis with the introduction of iron cations as a dopant the structure of hydroxyapatite, in which the dopant occupies the position of the calcium cation, is formed. This type of substitution is accompanied by a decrease in the lattice parameters of the hydroxyapatite. It is shown that iron cations have predominantly a 3+ charge, which is independent of the charge of the initial reagent containing the iron cation. It was also found that in the process of mechanochemical synthesis under certain conditions, simultaneous partial replasement of calcium cations with iron cations and phosphate group with carbonate group can be realized. The powders obtained by mechanochemical synthesis were characterized by powder diffraction, infrared spectroscopy, near-edge X-ray absorption fine structure spectroscopy and Mössbauer spectroscopy.

About the authors

D. D. Isaev

Institute of Solid State Chemistry and Mechanochemistry, SB RAS; Novosibirsk State University; Institute of Mathematical Problems of Biology, RAS – Keldysh Institute of Applied Mathematics, Federal Research Center, RAS

Author for correspondence.
Email: isaev@solid.nsc.ru
Russia, 630090, Novosibirsk; Russia, 630090, Novosibirsk; Russia, 142290, Pushchino

V. V. Kriventsov

Boreskov Institute of Catalysis, Federal Research Center, SB RAS

Email: bulina@solid.nsc.ru
Russia, 630090, Novosibirsk

S. A. Petrov

Institute of Solid State Chemistry and Mechanochemistry, SB RAS

Email: bulina@solid.nsc.ru
Russia, 630090, Novosibirsk

V. S. Bystrov

Institute of Mathematical Problems of Biology, RAS – Keldysh Institute of Applied Mathematics, Federal Research Center, RAS

Email: bulina@solid.nsc.ru
Russia, 142290, Pushchino

N. V. Bulina

Institute of Solid State Chemistry and Mechanochemistry, SB RAS; Institute of Mathematical Problems of Biology, RAS – Keldysh Institute of Applied Mathematics, Federal Research Center, RAS

Author for correspondence.
Email: bulina@solid.nsc.ru
Russia, 630090, Novosibirsk; Russia, 142290, Pushchino

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Copyright (c) 2023 Д.Д. Исаев, В.В. Кривенцов, С.А. Петров, В.С. Быстров, Н.В. Булина