Ceramic materials of low-temperature sintering from natural and technogenic rocks of the Tuva Republic

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

Abroad, they are actively engaged in “cold” sintering of materials, including ceramic, which is a mechanically and thermally conditioned mass transfer process that allows for low-temperature integration of various materials. The paper presents the results of research on low-temperature sintering and optimization of firing regimes for ceramic materials by introducing a salt complex with a liquidus temperature of 825оC into a charge based on natural and man-made rocks of the Republic of Tyva. The optimal concentrations of salt-containing additives in the ceramic mass, which affect the roasting properties of the resulting materials, have been determined. It was found that the introduction of a complex of salts into the ceramic charge promotes earlier sintering of the shard and the production of high-quality wall ceramics at lower temperatures, which leads to a reduction in energy costs during firing of products.

Full Text

Restricted Access

About the authors

G. I. Storozhenko

Novosibirsk State University of Architecture and Civil Engineering (Sibstrin)

Author for correspondence.
Email: baskey_ltd@mail.ru

Doctor of Sciences (Engineering) Docent

Russian Federation, 113, Leningradskaya Street, Novosibirsk, 630008

T. V. Sapelkina

Tuva Institute of Integrated Development of Natural Resources, Siberian Branch of the Russian Academy of Sciences

Email: sapelkina_geotom@mail.ru

Research Assistant 

Russian Federation, 117A, Internatsionalnaya Street, Kyzyl, Tyva Republic, 667007

Т. Е. Shoeva

Novosibirsk State University of Architecture and Civil Engineering (Sibstrin)

Email: shoeva_geotom@mail.ru

Candidate of Sciences (Engineering) 

Russian Federation, 113, Leningradskaya Street, Novosibirsk, 630008

I. M. Sebelev

Novosibirsk State University of Architecture and Civil Engineering (Sibstrin)

Email: i.sebelev@sibstrin.ru

Doctor of Sciences (Engineering), Docent 

Russian Federation, 113, Leningradskaya Street, Novosibirsk, 630008

References

  1. On the approval of the Information and Technical Handbook on the best available technologies «Production of ceramic products.» ITS 4-2023. Moscow: GTC. 2023. 368 p. (In Russian).
  2. Shishakina O.A., Palamarchuk A.A. Application of fluxes in the production of ceramic materials. Mezhdunarodnyy zhurnal prikladnykh i fundamental’nykh issledovaniy. 2019. No. 11, pp. 105–109. (In Russian).
  3. Gurieva V.A., Dubinetskiy V.V., Vdovin K.M., Butrimova N.V. Wall ceramic on the basis of highly calcined raw materials of Orenburzhye. Stroitel’nye materialy [Construction Materials]. 2016. No. 12, pp. 55–58. (In Russian).
  4. Yatsenko N.D., Vilbitskaya N.A., Yatsenko A.I. Features of the formation of the phase composition and properties of high-calcium low-density ceramics based on clay raw materials of various chemical and mineralogical composition. Izvestiya of higher educational institutions. North Caucasian region. Series: Technical sciences. 2021. No. 2 (210), pp. 75–80. (In Russian). https://doi.org/10.17213/1560-3644-2021-2-75-80
  5. Dovzhenko I.G. Intensification of agglomeration of ceramic brick with application of the waste of aluminium manufacture. Fundamental’nye issledovaniya. 2011. No. 12 (2), pp. 341–344. (In Russian). https://fundamental-research.ru/ru/article/view?id=29085
  6. Storozhenko G.I. Technology for the production of wall ceramic products from activated clay raw materials. Diss. Doc. (Engineering). Tomsk. 2000. 231 p. (In Russian).
  7. Kara-Sal B.K. Ceramic building materials obtained by firing at reduced pressure (technology, structure and properties). Diss. Doc. (Engineering). Novosibirsk. 2007. 307 p. (In Russian).
  8. Kurnosov V.V., Tihonova V.R. Hood furnace – universal unit for burning ceramics. Stroitel’nye Materialy [Construction Materials]. 2023. No. 5, pp. 48–52. (In Russian). https://doi.org/10.31659/0585-430X-2023-813-5-48-52
  9. Biesuz M., Saunders T.G., Grasso S., Speranza G., Sorarù G.D., Campostrini R., Sglavo V.M., Reece M.J. Flash joining of conductive ceramics in a few seconds by flash spark plasma sintering. Journal of the European Ceramic Society. 2019. Vol. 39. Iss. 15, pp. 4664–4672 https://doi.org/10.1016/j.jeurceramsoc.2019.07.036
  10. Guo J., Floyd R., Lowum S., Maria J.-P., Beauvoir T.H., Seo J.-H., Randall C.A. Cold sintering: progress, challenges, and future opportunities. Annual Review of Materials Research. 2019. Vol. 49. No. 7, pp. 275–295. https://doi.org/10.1146/annurev-matsci-070218-010041
  11. Galota A., Sglavo V.M. The cold sintering process: A review on processing features, densification mechanisms and perspectives. Journal of the European Ceramic Society. 2021. Vol. 41. No. 9, pp. 1–17. https://doi.org/10.1016/j.jeurceramsoc.2021.09.024
  12. Grasso S., Biesuz M., Zoli L., Taveri G., Duff A.I., Ke D., Jiang A., Reece M.J. A review of cold sintering processes. Advances in Applied Ceramics. 2020. Vol. 119, No. 1, pp. 115–143. http://dx.doi.org/10.1080/17436753.2019.1706825
  13. Guo H., Baker A., Guo J., Randall C.A. Cold sintering process: A novel technique for low-temperature ceramic processing of ferroelectrics. Journal American Ceramic Society. 2016. Vol. 99. No. 11, pp. 3489–3507. https://doi.org/10.1111/jace.14554
  14. Rowe J.J., Morey G.W., Zen C.S. The quinary reciprocal salt system Na, K, Mg, Ca/Cl, SO4; a review of the literature with new data. Washington: united states government printing office, 1972. 37 p. https://pubs.usgs.gov/pp/0741/report.pdf

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Fig. 1. Fusibility diagram of a salt system NaCl–K2SO4–CaSO4

Download (144KB)
Indexing metadata
3. Fig. 2. X-ray diffraction pattern of: a – Sukpak clay; b – Ust-Elegest mudstone

Download (45KB)
Indexing metadata

Copyright (c) 2024 ООО РИФ "СТРОЙМАТЕРИАЛЫ"