Kinetics the proliferation of correlations in multiple quantum NMR spectroscopy
- Authors: Bodneva V.L.1, Vetchinkin A.S.1, Lidskiy B.V.1, Lundin A.A.1, Umanskii S.Y.1, Chaikina Y.A.1, Shushin A.I.1
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Affiliations:
- Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
- Issue: Vol 44, No 1 (2025)
- Pages: 16-25
- Section: СТРОЕНИЕ ХИМИЧЕСКИХ СОЕДИНЕНИЙ, КВАНТОВАЯ ХИМИЯ, СПЕКТРОСКОПИЯ
- URL: https://rjsvd.com/0207-401X/article/view/683318
- DOI: https://doi.org/10.31857/S0207401X25010026
- ID: 683318
Cite item
Abstract
It is shown that the number of spins in clusters of coherently correlated states arising under conditions of multiplequantum NMR – spectroscopy in a solid increases exponentially with time. The Smolukhovsky equation was used to study the above processes. Possible processes of cluster degradation were not taken into account. The results obtained are in good agreement with the experimental data, at least up to about 105 spins in the cluster.
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About the authors
V. L. Bodneva
Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: ya-andylun2012@yandex.ru
Russian Federation, Moscow
A. S. Vetchinkin
Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: ya-andylun2012@yandex.ru
Russian Federation, Moscow
B. V. Lidskiy
Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: ya-andylun2012@yandex.ru
Russian Federation, Moscow
A. A. Lundin
Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: ya-andylun2012@yandex.ru
Russian Federation, Moscow
S. Y. Umanskii
Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: ya-andylun2012@yandex.ru
Russian Federation, Moscow
Y. A. Chaikina
Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: ya-andylun2012@yandex.ru
Russian Federation, Moscow
A. I. Shushin
Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences
Email: ya-andylun2012@yandex.ru
Russian Federation, Moscow
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