Mononuclear diphenyltin (IV) complexes with salicylaldimine Schiff bases. Synthesis, structure, electrochemical properties

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New mononuclear tin(IV) complexes were obtained by condensation diphenyltin oxide Ph2SnO with a number of Schiff bases containing hydrazone fragment. The structure of the complexes was confirmed by 1H, 13C and 119Sn NMR spectroscopy, as well as by X-ray diffraction analysis (CCDC 2443096 (IV) и 2443095 (V)). The electronic and redox properties of complexes I–V, including the value of the energy gap, were studied using UV spectroscopy and cyclic voltammetry. Electrochemical oxidation and reduction of complexes I, II, IV and V are irreversible and accompanied by further chemical transformations. Unlike them electroreduction of complex III with a pincer ligand leads to the formation of persistent anion-radical particles.

作者简介

P. Shangin

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

Email: en@ioc.ac.ru
Москва, Россия

V. Klok

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

Email: en@ioc.ac.ru
Москва, Россия

I. Krylova

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

Email: en@ioc.ac.ru
Москва, Россия

M. Minyaev

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

Email: en@ioc.ac.ru
Москва, Россия

E. Tretyakov

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

Email: en@ioc.ac.ru
Москва, Россия

M. Syroeshkin

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

Email: en@ioc.ac.ru
Москва, Россия

V. Pechennikov

First Moscow State Medical University, Moscow, Russia

Email: en@ioc.ac.ru
Москва, Россия

M. Egorov

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

Email: en@ioc.ac.ru
Москва, Россия

E. Nikolaevskaya

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

编辑信件的主要联系方式.
Email: en@ioc.ac.ru
Москва, Россия

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