Synthesis and structural features of Co(II) compounds with 3-arylidene-1-pyrroline derivatives and monocarboxylic acids anions

Yu. K. Voronina; Воронина Ю. К.; O. V. Zvereva; Зверева О. В.; M. A. Shmelev; Шмелев М. А.; E. N. Zorina-Tikhonova; Зорина-Тихонова Е. Н.; A. V. Rogachev; Рогачев А. В.; A. A. Sidorov; Сидоров А. А.; I. L. Eremenko; Еременко И. Л.

doi:10.31857/S0132344X25050071

Synthesis and structural features of Co(II) compounds with 3-arylidene-1-pyrroline derivatives and monocarboxylic acids anions

Authors: Voronina Y.K.¹, Zvereva O.V.¹^,2, Shmelev M.A.¹, Zorina-Tikhonova E.N.¹, Rogachev A.V.³, Sidorov A.A.¹, Eremenko I.L.¹
Affiliations:
1. N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
2. A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
3. MIREA — Russian Technological University
Issue: Vol 51, No 5 (2025)
Pages: 343-352
Section: Articles
URL: https://rjsvd.com/0132-344X/article/view/685417
DOI: https://doi.org/10.31857/S0132344X25050071
EDN: https://elibrary.ru/KVJOUQ
ID: 685417

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract

A series of acetate and trifluoroacetate compounds of cobalt(II) with derivatives of 3-arylidene-1-pyrrolines (X-L; X = Cl, OH) as N-donor ligands was synthesized. Varying the synthesis and crystallization conditions made it possible to obtain coordination compounds of various compositions and structures: a tetranuclear complex based on a cubane fragment {Co₄(OH)₄}^4– — [Co₄(OH)₄(Cl–L)₄(OAc)₄] (I), a 1D-polymer complex [Co(H₂O)(Cl–L)₂(CF₃COO)_1.167(OAc)_0.833]_n (II) or a molecular complex [Co(OH–L)₂(OAc)₂] (III). The synthesized compounds were characterized by X-ray diffraction, IR spectroscopy and CHN analysis. The structure and crystal packing of the obtained complexes were analyzed in detail, the main structure-forming non-covalent interactions in crystals were identified.

Keywords

cobalt, 3-arylidene-1-pyrrolines, X-ray structural analysis, non-covalent interactions

Full Text

References

Keller L.-A., Merkel O., Popp A. // Drug Deliv Transl Res. 2022. V. 12. № 4. P. 735.
Jeong W.Y., Kwon M., Eun Choi H., Su Kim K. // Biomater Res. 2021. V. 25. № 1. P. 24.
Thomford N.E., Senthebane D.A., Rowe A. et al. // Int. J. Mol. Sci. 2018. V. 19. № 6. Р. 1578.
Krasnovskaya O., Naumov A., Guk D. et al. // Int. J. Mol. Sci. 2020. V. 21. № 11. Р. 3965.
Psomas G. // Coord. Chem. Rev. 2020. V. 412. P. 213259.
Ghanghas P., Choudhary A., Kumar D., Poonia K. // Inorg. Chem. Commun. 2021. V. 130. P. 108710.
El-Gammal O.A., Mohamed F.S., Rezk G.N., ElBindary A.A. // J. Mol. Liq. 2021. V. 330. P. 115522.
Pellei M., Del Bello F., Porchia M., Santini C. // Coord. Chem. Rev. 2021. V. 445. P. 214088.
Uvarova M.A., Lutsenko I.A., Shmelev M.A. et al // New. J. Chem. 2024. V. 48. № 2. P. 717.
Shmelev M.A., Chistyakov A.S., Razgonyaeva G.A. et al. // Crystals. 2022. V. 12. № 4. Р. 508.
Leung C.-H., Zhong H.-J., Chan D. S.-H. et al. // Coord. Chem. Rev. 2013. V. 257. № 11‒12. P. 1764.
Ronconi L., Sadler P.J. // Coord. Chem. Rev. 2007. V. 251. № 13‒14. P. 1633.
Liu W., Gust R. // Coord. Chem. Rev. 2016. V. 329. P. 191.
Bazhina E.S., Bovkunova A.A., Shmelev M.A. et al. // Inorg. Chim. Acta. 2023. V. 547. Р. 121359.
Klintworth R., de Koning C.B., Opatz T., Michael J.P. // J. Org. Chem. 2019. V. 84. № 17. P. 11025.
Saraswat P., Jeyabalan G., Hassan M.Z. et al. // Synth. Commun. 2016. P. 1643.
Ahmad Bhat A., Singh I., Tandon N., Tandon R. // Eur. J. Med. Chem. 2023. V. 246. P. 114954.
Fernandes L. de P., Silva J.M.B., Martins D.O.S. et al. // Int. J. Mol. Sci. 2020. V. 21. № 21. P. 8355.
Delehanty J.B., Bongard J.E., Thach D.C. et al. // J. Biol. Chem. 2008. V. 16. № 2. P. 830.
Smolobochkin, A.V., Gazizov, A.S., Melyashova, A.S. et al. // RSC Advances. 2017. V. 7. № 80. P. 50955.
Rizbayeva T.S., Smolobochkin A.V, Gazizov A.S. et al. // J. Org. Chem. 2023. V. 88. P. 11855.
Sheldrick G.M. // Acta Crystallogr. C. 2015. V. 71. P. 3.
Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339.
Casanova D., Llunell M., Alemany P., Alvarez S. et al. // Chem. Eur. J. 2005. V. 11. P. 1479.
Lee S.Y., Kim N., Lee M.M. et al. // Dalton Trans. 2016. V. 45. P. 1727.
Nguyen A.I., Wang J., Levine D.S. et al. // Chem. Sci. 2017. V. 8. P. 4274.
Zhao H., Bacsa J., Dunbar K.R. // Acta Crystallogr. E. 2004. V. 60. P. m637.
Fomina I.G., Dobrokhotova Zh.V, Aleksandrov G.G. et al. // Russ. Chem. Bull. 2009. V. 58. P. 11.
Newton G.N., Cooper G.J.T., Kögerler P. et al. // J. Am. Chem. Soc. 2008. V. 130. P. 790.
Cooper G.J.T., Newton G.N., Kogerler P. et al. // Angew. Chem. Int. Ed. 2007. V. 46. P. 1340.
Andaloussi Y.H., Sensharma D., Bezrukov A.A et al. // Cryst. Growth. Des. 2023. V. 23. P. 3019. https://doi.org/10.1021/acs.cgd.3c00094
Zvereva O.V., Rizbaeva T.S., Shmelev M.A. et al. // J. Struct. Chem. 2024. V. 65. № 7. P. 1439.

Supplementary files

Supplementary Files

Action

1. JATS XML

Download

2. Fig. 1. Structure of the molecule (a) and fragment of the crystal packing (b) of compound I.

Download (752KB)

Indexing metadata

3. Fig. 2. Structure of the monomer fragment (a), fragment of the polymer chain (b) and fragment of the crystal packing (c) of coordination polymer II.