Synthesis and structure of gold(III) compounds with i-Pr- and t-Bu- substituted tetraarylporphyrins

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Abstract

Gold(III) compounds with tetrakis-(4-tert-butylphenyl)porphyrin, [Au(TTBPP)][AuCl4] (I), and with tetrakis-(4-isopropylphenyl)porphyrin, [Au(TIPPP)][AuCl4] (II), were synthesized for the first time. The obtained compounds were characterized by elemental analysis,1H NMR spectroscopy, cyclic voltammetry, and X-ray diffraction analysis of solvated complexes (CCDC no. 2333206 (Ia) and 2333207 (IIa)). Study of the structures of the obtained gold(III) complexes confirmed their specific character consisting in the formation of additional Au⋅⋅⋅Au and Au⋅⋅⋅Cl contacts between neighboring complexes giving weak intermolecular bonds.

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About the authors

E. E. Bardina

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk

E. V. Makotchenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk

K. P. Birin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Russian Federation, Moscow

E. S. Shremzer

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Russian Federation, Moscow

P. A. Abramov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk

Yu. G. Gorbunova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Russian Federation, Moscow; Moscow

A. L. Gushchin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk

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Supplementary files

Supplementary Files
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2. Sch. 1. Structure of porphyrins and their abbreviation.

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3. Sch. 2. Synthesis of compounds I and II.

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4. Fig. 1. ESP of TTBPPPH2 and [Au(TTBPPP)][AuCl4] (I) in CH2Cl2.

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5. Fig. 2. ESP of TIPPPPPH2 and [Au(TIPPPP)][AuCl4] (II) in CH2Cl2.

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6. Fig. 3. Molecular structure of the complex cation in structure Ia according to PCA data.

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7. Fig. 4. Molecular structure of the complex cation in structure IIa according to PCA data.

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8. Fig. 5. Fragment of crystal structure Ia. Au⋅⋅⋅⋅Au and Au⋅⋅⋅⋅Cl contacts are shown by dashed lines.

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9. Fig. 6. Fragment of the crystal structure IIa. The Au⋅⋅⋅⋅Au and Au⋅⋅⋅⋅Cl contacts are shown by dashed lines.

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