Heterophase Synthesis of Silver Trifluoroacetate with Copper, Indium, and Zinc. Standard Enthalpy of Formation of Copper Trifluoroacetate

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Abstract

Solid-phase reactions of silver trifluoroacetate CF3COOAg with copper, indium, and zinc are studied by thermogravimetry, differential scanning calorimetry, and mass spectrometry. In a temperature range of 358–428 K, the reactions are found to afford trifluoroacetates of these metals without mass loss of the weighed samples. The obtained experimental data make it possible to calculate the enthalpy of formation of copper trifluoroacetate H298 (CF3СООСu, cr) = –1020.5 ± 18.0 kJ/mol.

About the authors

I. P. Malkerova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sidorov@igic.ras.ru
Россия, Москва

D. B. Kayumova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sidorov@igic.ras.ru
Россия, Москва

E. V. Belova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sidorov@igic.ras.ru
Россия, Москва

M. A. Shmelev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: shmelevma@yandex.ru
Россия, Москва

A. A. Sidorov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sidorov@igic.ras.ru
Россия, Москва

I. L. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: sidorov@igic.ras.ru
Россия, Москва

A. S. Alikhanyan

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Author for correspondence.
Email: alikhan@igic.ras.ru
Россия, 119991, Москва, Ленинский пр-т, 31

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Copyright (c) 2023 И.П. Малкерова, Д.Б. Каюмова, Е.В. Белова, М.А. Шмелев, А.А. Сидоров, И.Л. Еременко, А.С. Алиханян