Low-temperature behavior of heat capacity and pho-toluminescence of a binuclear pivalate complex [Eu2(bath)2(piv)6]

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Abstract

The low-temperature behavior of the heat capacity and photoluminescence of the previously structurally characterized binuclear pivalate complex [Eu2(bath)2(piv)6] (monoclinic, I2/a) (1), where bath = 4,7-diphenyl-1,10-phenanthroline, piv = (CH3)3CCO2-. Using the adiabatic calorimetry method, the temperature dependence of the heat capacity was measured in the temperature range 5.96–302.88 K and the thermodynamic functions Cp0(T), S0(T), Ф0(Т) and Н0(Т) - Н0(0) were calculated. The absence of low-temperature phase transformations of complex 1 was shown. It was established that in the temperature range 98-295 K, complex 1 demonstrates high temperature stability of the integral intensity of photoluminescence of the transitions of the Eu3+ ion 5D0-7Fj (j = 0.6).

About the authors

I. G. Fomina

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: fomina@igic.ras.ru
Россия, Москва

A. V. Tyurin

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Email: fomina@igic.ras.ru
Россия, Москва

Yu. S. Zavorotny

Scobeltsyn Nuclear Physics Research Institute of the Moscow State University

Email: fomina@igic.ras.ru
Россия, Москва

I. L. Eremenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Author for correspondence.
Email: fomina@igic.ras.ru
Россия, Москва

References

  1. Huang C.-H. Rare Earth Coordination Chemistry: Fundamentals and Applications. Singapore: John Wiley & Sons Pte Ltd, 2010. 575 p.
  2. Binnemans K. // Handbook on the Physics and Chemistry of Rare Earths / Eds. Gschneidner K.A. Jr., Bünzli J.-C.G., Pecharsky V.K.). Amsterdam: Elsevier, 2005. V. 35. P. 107.
  3. Gatteschi D., Sessoli R., Villain J. Molecular Nanomagnets. Oxford University Press: Oxford, 2006. 408 p.
  4. Metal Ions in Biological Systems: The Lanthanides and Their Interrelations with Biosystems / Eds. Sigel H., Sigel A. Basel: Marcel Dekker, 2003. V. 40.
  5. Lan Y.-Q., Jiang H.-L., Li S.-L. et al. // Inorg. Chem. 2012. V. 51. P. 7484.
  6. Zhu Y., Luo F., Luo M. et al. // Dalton Trans. 2013. V. 42. P. 8545.
  7. Bunzli J.-C.G., Chauvin A.-S., Kim H.K. et al. // Coord. Chem. Rev. 2010. V. 254. P. 2623.
  8. Shavaleev N.M., Scopelliti R., Gumy F. et al. // Inorg. Chem. 2009. V. 48. P. 6178.
  9. Shavaleev N.M., Gumy F., Scopelliti R. et al. // Inorg. Chem. 2009. V. 48, P. 5611.
  10. Fomina I.G., Dobrokhotova Zh.V., Ilyukhin A.B. et al. // Polyhedron. 2013. V. 65. P. 152.
  11. Law G.-L., Kwok W.-M., Wong W.-T. et al. // J. Phys. Chem. B. 2007. V. 111. P. 10858.
  12. Brito H.F., Malta O.L., Felinto M.C.F.C., Teotonio E.E.S. // The Chemistry of Metal Enolates / Ed. Zabicky J. John Chichester (England): Wiley & Sons Ltd., 2009. Ch. 3. P. 131.
  13. Fomina I.G., Dobrokhotova Zh.V., Aleksandrov G.G. et al. // Polyhedron. 2013. V. 50. P. 297.
  14. Fomina I.G., Dobrokhotova Zh.V., Ilyukhin A.B., et al. // Dalton Trans. 2014. V. 43. P. 18104.
  15. Фомина И.Г., Доброхотова Ж.В., Илюхин А.Б. и др. // Изв. АН. Сер. хим. 2014. Т. 63. № 4. С. 938 (Fomina I.G., Dobrokhotova Zh.V., Ilyukhin A.B. et al. // Russ. Chem. Bull. 2014. V. 63. № 4. P. 938). https://doi.org/10.1007/s11172-014-0531-9
  16. Fomina I.G., Ilyukhin A.B., Zavorotny Y.S. et al. // Polyhedron. 2017. V. 129. № ? P. 105.
  17. Fomina I.G., Dolgushin F.M., Koroteev P.S. et al. // Eur. J. Inorg. Chem. 2021. V. 2021. № 5. P. 464.
  18. Доброхотова Ж.В., Фомина И.Г., Александров Г.Г. и др. // Журн. неорган. химии. 2009. Т. 54. № 5. С. 727. (Dobrokhotova Zh.V., Fomina I.G., Aleksandrov G.G. et al. // Russ. J. Inorg. Chem. 2009. V. 5. P. 668). https://doi.org/10.1134/S0036023609050040
  19. Fomina I.G., Dobrokhotova Zh.V., Kazak V.O. et al. // Eur. J. Inorg. Chem. 2012. V. 22. P. 3595.
  20. Малышев В.M., Мильнер Г.А., Соркин Е.Л. и др. // Приборы и техника эксперимента. 1985. № 6. С. 195).
  21. Varushchenko R.M., Druzhinina A.I., Sorkin E.L. // J. Chem. Thermodyn. 1997. V. 29. № 6. P. 623.
  22. Гуревич В.М., Хлюстов В.Г. // Геохимия. 1979. Т. 17. № 6. С. 829 (Gurevich V.M., Khluystov V.G. // Geokhimiya. 1979. V.17. № 6. P. 829).
  23. NIST ITS-90 Thermocouple Database. https://doi.org/10.18434/T4S888
  24. Гурвич А.М. Введение в физическую химию кристаллофосфоров. Учеб. пособие для втузов. М.: Высш. школа, 1971. С. 40.
  25. Carnall W.T., Crosswhite H.M. // Argonne Natl. Lab. Rept. 1977. P. ANL78XX95.
  26. Фомина И.Г., Кискин М.А, Мартынов А.Г. и др. // Журн. неорган. химии. 2004. Т. 49. № 9. С. 1463. (Fomina I.G., Kiskin M.A., Martynov A.G. et al. // Russ. J. Inorg. Chem. 2004. V. 49. P. 1349).
  27. Fomina I.G., Ilyukhin A.B., Gavrikov A.V. et al. // Inorg. Chim. Acta. 2018. V. 482. P. 8.
  28. Dobrokhotova Zh.V., Tyurin A.V., Fomina I.G. et al. // Thermochim. Acta. 2013. V. 556. P. 68.
  29. Доброхотова Ж.В., Фомина И.Г., Кискин М.А. и др. // Журн. физ. химии. 2006. Т. 80. № 3. С. 400. (Dobrokhotova Zh.V., Fomina I.G., Kiskin M.A. et al. // Russ. J. Phys. Chem. 2006. V. 3. P. 323). https://doi.org/10.1134/S0036024406030034
  30. Osad’ko I.S. // Phys. Rep. 1991. V. 206 № 2. P. 43.
  31. Золин В.Ф., Коренева Л.Г. Редкоземельный зонд в химии и биологии. М.: Наука, 1980. С. 350.
  32. Золотов Ю.А. Основы аналитической химии. Т. 2. М.: Академия, 2012. 408 с.
  33. Fomina I.G., Dobrokhotova Zh.V., Aleksandrov G.G. et al. // J. Solid State Chem. 2012. V. 185. P. 49.
  34. Малкерова И.П., Алиханян А.С., Фомина И.Г. и др. // Журн. неорган. химии. 2009. Т. 54. № 5. С. 793 (Malkerova I.P., Alikhanyan A.S., Fomina I.G. et al. // Russ. J. Inorg. Chem. 2009. V. 54. № 5. P. 734). https://doi.org/10.1134/S0036023609050118
  35. Малкерова И.П., Алиханян А.С., Фомина И.Г. и др. // Журн. неорган. химии. 2010. Т. 55. №1. С. 56 (Malkerova I.P., Alikhanyan A.S., Fomina I.G. et al. // Russ. J. Inorg. Chem. 2010. V. 55. №1. P. 53). https://doi.org/10.1134/S0036023610010109
  36. Емелина А.Л., Доброхотова Ж.В., Синельщикова А.А. и др. // Журн. неорган. химии. 2009. Т. 55. № 11. С. 1860 (Emelina A.L., Dobrokhotova Zh.V., Sinelshchikova A.A. et al. // Russ. J. Inorg. Chem. 2009. V. 55. № 11. P. 1754). https://doi.org/10.1134/S0036023610110124

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