Chemical transformations of bimetallic complex [Pd(OOCMe)4Mn] in reactions with 1,10-phenanthroline, pivalic acid and 5-nitro-1,10-phenantroline

E. A. Sosunov; Сосунов Е. А.; A. D. Maksimova; Максимова А. Д.; I. A. Yakushev; Якушев И. А.; N. K. Ogarkova; Огаркова Н. К.; M. N. Vargaftik; Варгафтик М. Н.; A. S. Popova; Попова А. С.

doi:10.31857/S0132344X23700330

Chemical transformations of bimetallic complex [Pd(OOCMe)4Mn] in reactions with 1,10-phenanthroline, pivalic acid and 5-nitro-1,10-phenantroline

Authors: Sosunov E.A.¹, Maksimova A.D.¹, Yakushev I.A.¹, Ogarkova N.K.¹, Vargaftik M.N.¹, Popova A.S.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
Issue: Vol 49, No 12 (2023)
Pages: 772-781
Section: Articles
URL: https://rjsvd.com/0132-344X/article/view/667637
DOI: https://doi.org/10.31857/S0132344X23700330
EDN: https://elibrary.ru/HINRJX
ID: 667637

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Abstract

A number of new bimetallic acetate and pivalate complexes of the Pd–Mn system have been synthesized and structurally characterized. The starting complex [Pd(OOCMe)4Mn] reacts with N donor ligands such as 1,10-phenanthroline to form [Pd(OOCMe)4Mn(phen)]·MeCN (I) (CIF file CCDC no. 2217716). The reactions of substitution of acetate bridges for pivalate bridges in heterometallic carboxylate Pd–Mn complexes have been studied; It has been shown that complete replacement of all acetate bridges with pivalate bridges is possible both in the heterometallic complex (I), in which there is a ligand coordinated to an additional metal atom, with the formation of the compound [Pd(Piv)4Mn(phen)]·C6H6, (II) ( CIF file CCDC No. 2217717), structurally close to the original acetate complex, and in the acetate complex [Pd(OOCMe)4Mn]. The heterometallic pivalate cocrystallizate [Pd(Piv)4Mn 2HPiv] (III) obtained in the latter case (CIF file CCDC No. 2217718) is capable of reacting with 5-nitro-1,10-phenanthroline to form the complex [Pd(Piv)4Mn( nphen)] (IV) (CIF file CCDC No. 2217719).

Keywords

palladium, manganese, heterometallic complexes, synthesis, X-ray diffraction analysis, crystal chemistry

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