Mononuclear nickel(II) and copper(II) coordination compounds with ligands based on acetyl(benzoyl)acetone S-methylisothiosemicarbazones and 8-quinolinecarboxaldehyde. Synthesis and crystal structure

M. А. Cocu; Коку М. А.; P. N. Bourosh; Боурош П. Н.; V. K. Kravtsov; Кравцов В. Х.; О. S. Danilescu; Данилеску О. С.; I. I. Bulhac; Булхак И. И.

doi:10.31857/S0132344X24030061

Mononuclear nickel(II) and copper(II) coordination compounds with ligands based on acetyl(benzoyl)acetone S-methylisothiosemicarbazones and 8-quinolinecarboxaldehyde. Synthesis and crystal structure

Authors: Cocu M.А.¹, Bourosh P.N.¹, Kravtsov V.K.¹, Danilescu О.S.¹^,2, Bulhac I.I.¹
Affiliations:
1. Moldova State University
2. Technical University of Moldova,
Issue: Vol 50, No 3 (2024)
Pages: 209-219
Section: Articles
URL: https://rjsvd.com/0132-344X/article/view/667614
DOI: https://doi.org/10.31857/S0132344X24030061
EDN: https://elibrary.ru/NSHKZV
ID: 667614

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Abstract

Template condensation of S-methylisothiosemicarbazones of acetyl- or benzoylacetone with 8-quinolinecarboxaldehyde in the presence of nickel(II) and copper(II) ions gave four new mononuclear coordination compounds [NiL¹]I (I), [CuL¹I] (II), [NiL²]I (III) и [CuL²I] (IV). The chemical composition of the products was confirmed by elemental analysis, IR spectroscopy, and mass spectrometry, and the crystal structure of compounds I and II was determined by X-ray diffraction analysis (CCDC no. 2266386, 2266387). X-ray diffraction study revealed a square planar coordination environment of the central ion of the cationic Ni(II) complex and square pyramidal geometry for the molecular Cu(II) complex.

Keywords

nickel(II), copper(II), coordination compound, S-methylisothiosemicarbazones, X-ray diffraction analysis

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Moldova, Republic of, Chisinau

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