Second Example of a Cubane-Like Nickel(II) Complex in a Series of N-Derivatives of Taurine

E. O. Zemlyakova; Землякова Е. О.; L A. Khamidullina; Хамидуллина Л. А.; I. S. Puzyrev; Пузырев И. С.; P. D. Tobysheva; Тобышева П. Д.; Yu. S. Petrova; Петрова Ю. С.; L. K. Neudachina; Неудачина Л. К.; P. A. Slepukhin; Слепухин П. А.; A. V. Pestov; Пестов А. В.

doi:10.31857/S0132344X2260045X

Second Example of a Cubane-Like Nickel(II) Complex in a Series of N-Derivatives of Taurine

Authors: Zemlyakova E.O.¹, Khamidullina LA.¹^,2, Puzyrev I.S.¹, Tobysheva P.D.¹, Petrova Y.S.², Neudachina L.K.², Slepukhin P.A.¹, Pestov A.V.¹^,2
Affiliations:
1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia
2. Ural Federal University named after the first President of Russia B.N. Yeltsin, Yekaterinburg, Russia
Issue: Vol 49, No 7 (2023)
Pages: 441-448
Section: Articles
URL: https://rjsvd.com/0132-344X/article/view/667499
DOI: https://doi.org/10.31857/S0132344X2260045X
EDN: https://elibrary.ru/TUZEZI
ID: 667499

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Abstract

A new homometallic cubane-like nickel(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid [Ni4L4(OH)4]·2H2O (I) is synthesized, and its structure is studied by X-ray diffraction (XRD) (CIF file CCDC no. 2211359). In crystals of the complex, the metallocenters are joined into tetrahedra with the Ni…Ni distances (3.144–3.201 Å) supplemented to cubanes by the μ3-bridging oxygen atoms of the hydroxy groups. The coordination environment of each metallocenter is a distorted octahedron. The ligand is deprotonated, exists in the facial conformation, and performs the tridentate function to form two six-membered conjugated chelate cycles.

Keywords

cubane-like nickel(II) complex, N-derivatives of taurine, complex formation, XRD

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