Coordination Polymers of Lithium Based on 1,2-Bis[(2,6-diisopropyl-4-diethylmalonophenyl)imino]acenaphthene

N. L. Bazyakina; Базякина Н. Л.; V. G. Sokolov; Соколов В. Г.; M. V. Moskalev; Москалев М. В.; E. V. Baranov; Баранов Е. В.; I. L. Fedushkin; Федюшкин И. Л.

doi:10.31857/S0132344X23700263

Coordination Polymers of Lithium Based on 1,2-Bis[(2,6-diisopropyl-4-diethylmalonophenyl)imino]acenaphthene

Authors: Bazyakina N.L.¹, Sokolov V.G.¹, Moskalev M.V.¹, Baranov E.V.¹, Fedushkin I.L.¹
Affiliations:
1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia
Issue: Vol 49, No 7 (2023)
Pages: 387-397
Section: Articles
URL: https://rjsvd.com/0132-344X/article/view/667493
DOI: https://doi.org/10.31857/S0132344X23700263
EDN: https://elibrary.ru/TVUCKI
ID: 667493

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Abstract

1,2-Bis[(2,6-diisopropyl-4-diethylmalonophenyl)imino]acenaphthene (Dem-Bian) with zinc chloride forms complex [(Dem-Bian)ZnCl2] (I). The reaction of complex I with n-BuLi proceeds with the deprotonation of the malonate fragments and gives 1D coordination polymer [ZnCl2(Dem-Bian)Li(DME)2]n (II). The reaction of [(Dem-Bian)CuCl] with n-BuLi affords 1D polymer [(Dem-Bian)Li2(DME)2]n (III). Compounds I–III are characterized by elemental analysis and IR spectroscopy. Derivatives I and II are characterized by 1Н NMR spectroscopy. The crystal structures of compounds II and III are determined by X-ray diffraction (XRD). Their thermal stability is studied by thermogravimetric analysis.

Keywords

1,2-bis(arylimino)acenaphthene, organolithium coordination polymers, crystal structure

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