SYNTHESIS AND THERMODYNAMIC INVESTIGATIONS OF COMPOUND ON THE BASIS OF BISMUTH AND ITTERBIUM OXIDES

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Abstract

In the paper, compound with composition Bi1.3Yb0.7O3 was prepared by solid state reactions. It was shown that compound had cubic structure, space group Fm3m, lattice parameter a = 0.54202 nm. The dissolution enthalpy of compound Bi1.3Yb0.7O3 was measured by solution calorimetry in 2 M HCl and was ∆solH0 = −227.8 ± 6.3 kJ mol−1. Based on measured enthalpy of dissolution, the standard formation enthalpy of Bi1.3Yb0.7O3 was calculated as following value: ∆fH0 = −996.0 ± 7.9 kJ mol −1. Using Born-Haber cycle, the lattice enthalpy for Bi1.3Yb0.7O3 was calculated: ∆latH0 = −13278 kJ mol−1.

About the authors

N. I. Matskevich

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia

E. R. Elbaev

Nikolaev Institute of Inorganic Chemistry SB RAS; Novosibirsk State Technical University

Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia; Karl Marks Avenue, 20, Novosibirsk, 630073 Russia

A. N. Semerikova

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia

A. Y. Manakov

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia

L. M. Levchenko

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia

A. A. Shapovalova

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia

V. P. Zaitsev

Siberian State University of Water Transport

Email: nata.matskevich@yandex.ru
Shchetinkina Avenue, 33, Novosibirsk, 630033 Russia

E. N. Tkachev

Nikolaev Institute of Inorganic Chemistry SB RAS

Author for correspondence.
Email: nata.matskevich@yandex.ru
Lavrentiev Avenue, 3, Novosibirsk, 630090 Russia

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