INFLUENCE OF THE STRUCTURE OF PHOSPHORYL- AND CARBONYL CONTAINING PODANDS ON THE EXTRACTION OF LANTHANOIDS(III) FROM NITRIC ACID SOLUTIONS IN THE PRESENCE OF AN IONIC LIQUID -1-BUTYL-3-METHYLIMIDAZOLIUM BIS[(TRIFLUOROMETHYL)SULFONYL]IMIDE

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Abstract

The interphase distribution of lanthanoids(III) ions between aqueous solutions of HNO3 and solutions of tetrabutyldiglisolamide Bu2C(O)CH2OCH2C(O)NBu2(1), compounds R2P(O)CH2OCH2C(O)NBu2R = Bu (2), R = Ph (3) and phosphoryl-containing podands R2P(O)CH2OCH2P(O)R12R = R1= Bu (4); R = Bu, R1= Ph (5); R = R1= Ph (6)in 1,2-dichloroethane and ionic liquid - 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide has been studied. It has been established that the extraction of metal ions increases significantly in the presence of ionic liquids in the organic phase. The stoichiometry of the extracted complexes was determined, and the influence of the concentration of HNO3 in the aqueous phase and the structure of the extractant on the efficiency of extraction of metal ions into the organic phase was considered.

About the authors

A. N. Turanov

Osipyan Institute of Solid State Physics RAS

Chernogolovka, Russia

V. K. Karandashev

Institute of Microelectronics Technology and High Purity Materials RAS

Email: karan@iptm.ru
Chernogolovka, Russia

A. V. Kharlamov

LLC “VODECO”

Moscow, Russia

N. A. Bondarenko

National Research Center "Kurchatov Institute"

Moscow, Russia

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