Structure of the Local Environment and Hyperfine Interactions of  57 Fe Probe Nuclei in AMnO 3  (A = Sc, In)

A. V. Sobolev; Соболев А. В.; S. Šandalova; Шандалова С.; M. N. Smirnova; Смирнова М. Н.; A. A. Belik; Белик А. А.; Ya. S. Glazkova; Глазкова Я. С.; I. A. Presniakov; Пресняков И. А.

doi:10.31857/S0044457X23600779

Structure of the Local Environment and Hyperfine Interactions of ⁵⁷Fe Probe Nuclei in AMnO₃ (A = Sc, In)

Authors: Sobolev A.V.¹, Šandalova S.¹, Smirnova M.N.², Belik A.A.³, Glazkova Y.S.¹, Presniakov I.A.¹^,4
Affiliations:
1. Moscow State University
2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
3. Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS)
4. Shenzhen MSU-BIT University
Issue: Vol 68, No 10 (2023)
Pages: 1364-1372
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjsvd.com/0044-457X/article/view/666165
DOI: https://doi.org/10.31857/S0044457X23600779
EDN: https://elibrary.ru/EWUTKV
ID: 666165

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Abstract
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Abstract

The results of a Mössbauer study of hyperfine interactions of 57Fe probe nuclei in isostructural hexagonal manganites h-ScMnO3 and h-InMnO3 are presented. The results of measurements of the Mössbauer spectra at T > TN, as well as calculations of the parameters of the electric field gradient tensor at 57Fe nuclei, demonstrated different behavior of the probe iron ions in these isostructural systems, reflecting the difference in the processes of defect formation in their crystal lattices. On the contrary, measurements at T < TN did not reveal any differences in the local magnetic structure of 57Fe probe atoms in these oxides.

Keywords

hexagonal manganites, Mössbauer spectroscopy, ⁵⁷Fe probe atoms, antistructure defects

References

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