Transformations of Cerium Tetrafluoride Hydrate under Hydrothermal Conditions: A New Cerium Fluoride Hydrate Се 3 F 10  ⋅ 3Н 2 О

E. G. Il’in; Ильин Е. Г.; A. S. Parshakov; Паршаков А. С.; L. D. Iskhakova; Исхакова Л. Д.; S. Yu. Kottsov; Котцов С. Ю.; A. D. Filippova; Филиппова А. Д.; L. V. Goeva; Гоева Л. В.; N. P. Simonenko; Симоненко Н. П.; A. E. Baranchikov; Баранчиков А. Е.; V. K. Ivanov; Иванов В. К.

doi:10.31857/S0044457X23600688

Transformations of Cerium Tetrafluoride Hydrate under Hydrothermal Conditions: A New Cerium Fluoride Hydrate Се₃F₁₀ ⋅ 3Н₂О

Authors: Il’in E.G.¹, Parshakov A.S.¹, Iskhakova L.D.², Kottsov S.Y.¹, Filippova A.D.¹, Goeva L.V.¹, Simonenko N.P.¹, Baranchikov A.E.¹, Ivanov V.K.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Dianov Fiber Optics Research Center, Prokhorov Institute of General Physics, Russian Academy of Sciences
Issue: Vol 68, No 10 (2023)
Pages: 1348-1357
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjsvd.com/0044-457X/article/view/666162
DOI: https://doi.org/10.31857/S0044457X23600688
EDN: https://elibrary.ru/FXKZEP
ID: 666162

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Abstract

The behavior of cerium tetrafluoride hydrate was studied in water at a temperature of 80°C and under hydrothermal treatment at 100, 130, and 220°C for a day. The product of the hydrothermal treatment of CeF4·H2O at 100°C was investigated by chemical, thermogravimetric, IR spectroscopic, and X-ray powder diffraction analyses, which identified a new cerium fluoride with the composition, presumably, Ce3F10⋅3H2O or, most likely, (H3O)Ce3F10⋅2H2O. New compound crystallizes in the space group
with a unit cell parameter of 11.66 Å. Hydrothermal treatment of cerium tetrafluoride hydrate at temperatures above 130°C leads to hydrolysis and reduction of cerium(IV) fluoride compounds to form CeO2 and CeF3.

Keywords

cerium tetrafluoride, cerium trifluoride, cerium dioxide, rare earth elements

References

Lin H.-J., Li H.-W., Murakami H. et al. // J. Alloys Compd. 2018. V. 735. P. 1017. https://doi.org/10.1016/j.jallcom.2017.10.239
Liu G.K., Jursich G., Huang J. et al. // J. Alloys Compd. 1994. V. 213–214. P. 207. https://doi.org/10.1016/0925-8388(94)90905-9
Sun Y., Yang X., Mei H. et al. // ACS Omega. 2021. V. 6. № 17. P. 11348. https://doi.org/10.1021/acsomega.1c00332
Haase M., Schäfer H. // Angew. Chem. Int. Ed. 2011. V. 50. P. 5808. https://doi.org/10.1002/anie.201005159
Shan G.-B., Demopoulos G.P. // Adv. Mater. 2010. V. 22. P. 4373. https://doi.org/10.1002/adma.201001816
van der Ende B.M., Aarts L., Meijerink A. // Phys. Chem. Chem. Phys. 2009. V. 11(47). P. 11081. https://doi.org/10.1039/b913877c
Wang F., Liu X. // Chem. Soc. Rev. 2009. V. 38(4). P. 976. https://doi.org/10.1039/b809132n
Wang F., Banerjee D., Liu Y. et al. // Analyst. 2010. V. 135. P. 1839. https://doi.org/10.1039/c0an00144a
Chilingarov N.S., Knot’ko A.V., Shlyapnikov I.M. et al. // J. Phys. Chem. A. 2015. V. 119(31). P. 8452. https://doi.org/10.1021/acs.jpca.5b04105
Binnemans K. // Handbook on the Physics and Chemistry of Rare Earths. 2006. V. 36. P. 281. https://doi.org/10.1016/S0168-1273(06)36003-5
Furuya T., Kamlet A.S., Ritter T. // Nature. 2011. V. 473. P. 470. https://doi.org/10.1038/nature10108
Grzechnik A., Underwood C.C., Kolis J.W. et al. // J. Fluor. Chem. 2013. V. 156. P. 124. https://doi.org/10.1016/j.jfluchem.2013.09.002
Lopez C., Deschanels X., Bart J.M. et al. // J. Nucl. Mater. 2003. V. 312. P. 76. https://doi.org/10.1016/S0022-3115(02)01549-0
Marsac R., Réal F., Banik N.L. et al. // Dalton. Trans. 2017. V. 46. P. 13553. https://doi.org/10.1039/C7DT02251D
Schmidt R., Müller B.G. // Z. Anorg. Allg. Chem. 1999. V. 625. P. 605. https://doi.org/10.1002/(SICI)1521-3749(199904)62-5:4<605::AID-ZAAC605>3.0.CO;2-6
Zachariasen W.H. // Acta Crystallogr. 1949. V. 2. P. 388. https://doi.org/10.1107/S0365110X49001016
Brown D. // Halides of the Lanthanides and Actinides. New York: Wiley, 1968. 288 p.
Gabela F., Kojić-Prodić B., Šljukić M. et al. // Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1977. V. 33(12). P. 3733. https://doi.org/10.1107/S0567740877011960
Waters T.N. // J. Inorg. Nucl. Chem. 1960. V. 15. P. 320. https://doi.org/10.1016/0022-1902(60)80061-9
Hall D., Rickard C.E.F., Waters T.N. // Nature. 1965. V. 207. P. 405. https://doi.org/10.1038/207405b0
Gerasimenko A.V., Davidovich R.L., Tkachev V.V. et al. // Acta Crystallogr., Sect. E: Struct. Reports Online. 2006. V. 62(2). P. M196. https://doi.org/10.1107/S1600536805042479
Du Y., Yu J., Chen Y. et al. // Dalton. Trans. 2009. V. 2009. P. 6736. https://doi.org/10.1039/b902998b
Гельмбольдт В.О., Ганин Э.В., Короева Л.В. и др. // Журн. неорган. химии. 2001. Т. 46. № 11. С. 1833.
Рахматуллаев К., Талипов Ш.Т., Юсупова Р. // Докл. АН УзССР. 1962. № 4. P. 46.
Опаловский А.А. // Изв. СО АН СССР. 1964. Т. 67. С. 46.
Киселев Ю.М., Мартыненко Л.И., Спицын В.И. // Журн. неорган. химии. 1975. Т. 20. С. 576.
Asker W., Wylie A. // Aust. J. Chem. 1965. V. 18. № 7. P. 959. https://doi.org/10.1071/CH9650959
Il’in E.G., Parshakov A.S., Iskhakova L.D. et al. // J. Fluor. Chem. 2020. V. 236. P. 109576. https://doi.org/10.1016/j.jfluchem.2020.109576
Dawson J.K., D’Eye R.W.M., Truswell A.E. // J. Chem. Soc. 1954. P. 3922. https://doi.org/10.1039/jr9540003922
Champion M.J.D., Levason W., Reid G. // J. Fluor. Chem. 2014. V. 157. P. 19. https://doi.org/10.1016/j.jfluchem.2013.10.014
Il’in E.G., Parshakov A.S., Yarzhemsky V.G. et al. // J. Fluor. Chem. 2021. V. 251. P. 109897. https://doi.org/10.1016/j.jfluchem.2021.109897
Le Berre F., Boucher E., Allain M. et al. // J. Mater. Chem. 2000. V. 10. P. 2578. https://doi.org/10.1039/b002520h
Cheetham A.K., Fender B.E.F., Fuess H. et al. // Acta Crystallogr., Sect. B. 1976. V. 32. P. 94. https://doi.org/10.1107/S0567740876002380
Kuznetsov S.V., Osiko V.V., Tkatchenko E.A. et al. // Russ. Chem. Rev. 2006. V. 75. P. 1065. https://doi.org/10.1070/RC2006v075n12ABEH003637
Caron C., Boudreau D., Ritcey A.M. // J. Mater. Chem. C. 2015. V. 3. P. 9955. https://doi.org/10.1039/C5TC02527C
Andrrev O.V., Razumkova I.A., Boiko A.N. // J. Fluor. Chem. 2018. V. 207. P. 77. https://doi.org/10.1016/j.jfluchem.2017.12.001
Stephens N.F., Lightfoot P. // J. Solid State Chem. 2007. V. 180. P. 260. https://doi.org/10.1016/j.jssc.2006.09.032
Podberezskaya N.V., Potapova O.G., Borisov S.V. et al. // J. Struct. Chem. 1977. V. 17. P. 815. https://doi.org/10.1007/BF00746034
Fedorov P.P., Kuznetsov S.V., Osiko V.V. // Progress in Fluorine Science Series. Elsevier, 2016. P. 7. https://doi.org/10.1016/B978-0-12-801639-8.00002-7
Fedorov P.P., Mayakova M.N., Kuznetsov S.V. et al. // Nanosyst. Physics, Chem. Math. 2017. V. 8(4). P. 462. https://doi.org/10.17586/2220-8054-2017-8-4-462-470
Dzhabiev T.S., Tkachenko V.Y., Dzhabieva Z.M. et al. // Russ. J. Phys. Chem. A. 2020. V. 94(7). P. 1330. https://doi.org/10.1134/S0036024420060096
Kärkäs M.D., Verho O., Johnston E.V. et al. // Chem. Rev. 2014. V. 114. P. 11863. https://doi.org/10.1021/cr400572f
Prieur D., Bonani W., Popa K. et al. // Inorg. Chem. 2020. V. 59. P. 5760. https://doi.org/10.1021/acs.inorgchem.0c00506
Plakhova T.V., Romanchuk A.Y., Butorin S.M. et al. // Nanoscale. 2019. V. 11. P. 18142. https://doi.org/10.1039/c9nr06032d
Finkelnburg W., Stein A. // J. Chem. Phys. 1950. V. 18. P. 1296. https://doi.org/10.1063/1.1747929
Udayakantha M., Schofield P., Waetzig G.R. et al. // J. Solid State Chem. 2019. V. 270. P. 569. https://doi.org/10.1016/j.jssc.2018.12.017
Baenziger N.C., Holden J.R., Knudson G.E. et al. // J. Am. Chem. Soc. 1954. V. 76. P. 4734. https://doi.org/10.1021/ja01647a073
Zakiryanova I.D., Mushnikov P.N., Nikolaeva E.V. et al. // Processes. 2023. V. 11. P. 988. https://doi.org/10.3390/pr11040988