Synthesis, Chemical Structure, and Ground- and Excited-State Spectral Characteristics of (Porphyrinato)(chloro)indium(III) and Its Complexes with C60 and Pyridyl-Substituted Fullero[60]pyrrolidine

E. N. Ovchenkova; Овченкова Е. Н.; N. G. Bichan; Бичан Н. Г.; T. N. Lomova; Ломова Т. Н.

doi:10.31857/S0044457X23600652

Synthesis, Chemical Structure, and Ground- and Excited-State Spectral Characteristics of (Porphyrinato)(chloro)indium(III) and Its Complexes with C60 and Pyridyl-Substituted Fullero[60]pyrrolidine

Autores: Ovchenkova E.N.¹, Bichan N.G.¹, Lomova T.N.¹
Afiliações:
1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences
Edição: Volume 68, Nº 11 (2023)
Páginas: 1578-1587
Seção: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
URL: https://rjsvd.com/0044-457X/article/view/666141
DOI: https://doi.org/10.31857/S0044457X23600652
EDN: https://elibrary.ru/DJDWRN
ID: 666141

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Resumo

New complexes of [5,10,15,20-tetra-(4-methoxyphenyl)porphinato](chloro)indium(III) ((Cl)InTPP(p-OCH3)4) with unsubstituted C60 and 1-methyl-2-(pyridin-4'-yl)-3,4- fullero[60]pyrrolidine (PyC60) were synthesized in toluene. The stability constants of 1 : 1 complexes (dyads) were determined using UV-vis and fluorescence spectroscopy. The dyads were characterized by IR and 1H NMR spectroscopy data. It was established that fluorescence of (Cl)InTPP(p-OCH3)4 is quenched upon gradual addition of fullerenes. The numerical values of the Stern–Volmer quenching constants (KSV) were determined. The most important charge transfer characteristics of dyads (the lifetime of charge-separated states and charge separation and recombination constants), needed for further consideration of dyads based on indium(III) porphyrins as photoinduced electron transfer systems, were determined using femtosecond laser spectroscopy.

Palavras-chave

indium(III) porphyrin, C60 fullerene, fullero[60]pyrrolidine, donor-acceptor complex, formation reaction kinetics, spectral characteristics

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