NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure

O. P. Grigorieva; Григорьева О. П.; S. Yu. Stefanovich; Стефанович С. Ю.; D. O. Charkin; Чаркин Д. О.; V. A. Dolgikh; Долгих В. А.; K. A. Lysenko; Лысенко К. А.

doi:10.31857/S0044457X23600561

NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure

Authors: Grigorieva O.P.¹, Stefanovich S.Y.¹, Charkin D.O.¹, Dolgikh V.A.¹, Lysenko K.A.¹
Affiliations:
1. Chemistry Department, Moscow State University
Issue: Vol 68, No 11 (2023)
Pages: 1528-1536
Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
URL: https://rjsvd.com/0044-457X/article/view/666129
DOI: https://doi.org/10.31857/S0044457X23600561
EDN: https://elibrary.ru/DJQAEK
ID: 666129

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Abstract

Interaction of rare-earth oxides (Pr, Tb, Er) with periodic acid or sodium iodate under hydrothermal conditions in the presence of Na2HPO4⋅12H2O leads to formation of complex NaLn(IO3)4 iodates. The compounds of Pr and Tb are reported for the first time. Single-crystal studies reveal that they are isostructural to the previously reported analogs of other rare-earths and adopt the non-centrosymmetric space group Сс. Polycrystalline samples generate a strong SHG signal above that of the potassium dihydrogen phosphate reference standard. They also exhibit wide optical transparency areas and high thermal stability.

Keywords

rare-earth iodates, crystal structure, second harmonic generation

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