Problems in Imaging the Decomposition of Liquid and Solid Solutions in the Ag–Cu–Ni and Ag–Cu–Pb Systems

V. P. Vorob’eva; Воробьева В. П.; V. I. Lutsyk; Луцык В. И.; M. D. Parfenova; Парфенова М. Д.

doi:10.31857/S0044457X22600852

Problems in Imaging the Decomposition of Liquid and Solid Solutions in the Ag–Cu–Ni and Ag–Cu–Pb Systems

Authors: Vorob’eva V.P.¹, Lutsyk V.I.¹, Parfenova M.D.¹
Affiliations:
1. Physical Materials Science Institute, Siberian Branch, Russian Academy of Sciences
Issue: Vol 68, No 1 (2023)
Pages: 77-86
Section: ФИЗИКО-ХИМИЧЕСКИЙ АНАЛИЗ НЕОРГАНИЧЕСКИХ СИСТЕМ
URL: https://rjsvd.com/0044-457X/article/view/665327
DOI: https://doi.org/10.31857/S0044457X22600852
EDN: https://elibrary.ru/GVDGWT
ID: 665327

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Abstract

Three-dimensional (3D) computer models of Ag–Cu–Ni and Ag–Cu–Pb isobaric phase diagrams, designed based on 23 and 31 base points, respectively, assembled from 14 and 32 surfaces, 9 and 15 phase fields, respectively, and intended to digitize information on these diagrams, are used to verify the adequacy of interpretation of published isothermal and polythermal sections, both calculated and experimentally studied ones. The geometric features of the phase diagram regions that relate to liquid–liquid miscibility gaps and solid solution decomposition are refined in the 3D models. Mistakes arising from an incorrect imaging of the decay of copper–nickel solid solutions and from discrepancies in the values of the Ag–Cu–Pb ternary eutectic temperature are shown on polythermal sections.

Keywords

phase diagram, computer modeling, 3D imaging, lead-free solders, silver, copper, nickel, lead

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