Mixed Ligand Zinc Complexation with Ornithine and Histidine in Aqueous Solution

M. G. Nikitina; Никитина М. Г.; M. S. Gruzdev; Груздев М. С.; D. F. Pyreu; Пырэу Д. Ф.

doi:10.31857/S0044457X22700167

Mixed Ligand Zinc Complexation with Ornithine and Histidine in Aqueous Solution

Authors: Nikitina M.G.¹, Gruzdev M.S.¹, Pyreu D.F.²
Affiliations:
1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences
2. Ivanovo State University
Issue: Vol 68, No 3 (2023)
Pages: 363-372
Section: ФИЗИКОХИМИЯ РАСТВОРОВ
URL: https://rjsvd.com/0044-457X/article/view/665290
DOI: https://doi.org/10.31857/S0044457X22700167
EDN: https://elibrary.ru/JFWMYN
ID: 665290

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Abstract

The formation of mixed-ligand complexes of various compositions in the Zn–L-histidine (His)–L-ornithine (Orn) system has been studied by pH-metry, calorimetry, and NMR spectroscopy. The thermodynamic parameters (log K, ΔrG0 ΔrH, ΔrS) of the reactions of their formation at 298.15 K and ionic strength I = 0.5 (KNO3) have been calculated. Based on the comparative analysis of thermodynamic parameters, the most probable method for the coordination of amino acid residues in mixed complexes has been proposed.

Keywords

mixed ligand complexation, histidine, ornithine, calorimetry, zinc, denticity

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