Thermal Transformations of Porous Anodic Aluminum Oxide Formed in Sulfuric Acid/Oxalic Acid Mixed Electrolytes

I. V. Roslyakov; Росляков И. В.; I. V. Kolesnik; Колесник И. В.; M. A. Belokozenko; Белокозенко М. А.; A. D. Yapryntsev; Япрынцев А. Д.; K. S. Napolskii; Напольский К. С.

doi:10.31857/S0044457X22602061

Thermal Transformations of Porous Anodic Aluminum Oxide Formed in Sulfuric Acid/Oxalic Acid Mixed Electrolytes

Authors: Roslyakov I.V.¹^,2, Kolesnik I.V.², Belokozenko M.A.², Yapryntsev A.D.¹, Napolskii K.S.²
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Lomonosov Moscow State University
Issue: Vol 68, No 7 (2023)
Pages: 988-996
Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://rjsvd.com/0044-457X/article/view/665233
DOI: https://doi.org/10.31857/S0044457X22602061
EDN: https://elibrary.ru/RHMFAB
ID: 665233

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Abstract

Aluminum anodizing in electrolytes comprising mixtures of several acids opens way to manufacture porous films of anodic aluminum oxide (AAO) with a widely tunable structure period. Study of thermal transformations in AAO films produced in mixed electrolytes is a separate task, as a complex chemical composition of the material can give rise to some specifics in subsequent annealing. Impurity oxalate and sulfate ions were detected in the AAO produced by aluminum anodizing in sulfuric acid/oxalic acid mixed electrolytes. The sulfate weight fraction appears about one order of magnitude higher than the oxalate weight fraction, and it increases as the concentration ratio of sulfuric acid to oxalic acid in the electrolyte increases. In the same way, the crystallization temperature of amorphous AAO to a mixture of low-temperature Al2O3 polymorphs increases in response to increasing concentration ratio of sulfuric acid and oxalic acid. Thus, the component ratio in the mixed electrolyte used influences the composition and thermal transformations of AAO.

Keywords

anodic aluminum oxide, anodizing, sulfuric acid, oxalic acid, heat treatment

References

Domagalski J.T., Xifre-Perez E., Marsal L.F. // Nanomaterials. 2021. V. 11. P. 430. https://doi.org/10.3390/nano11020430
Petukhov D.I., Chernova E.A., Kapitanova O.O. et al. // J. Membr. Sci. 2019. V. 577. P. 184. https://doi.org/10.1016/j.memsci.2019.01.041
Roslyakov I.V., Petukhov D.I., Napolskii K.S. // Nanotechnology. 2021. V. 32. P. 33LT01. https://doi.org/10.1088/1361-6528/abfeea
Petukhov D.I., Kan A.S., Chumakov A.P. et al. // J. Membr. Sci. 2021. V. 621. P. 118994. https://doi.org/10.1016/j.memsci.2020.118994
Valeev R., Romanov E., Beltukov A. et al. // Phys. Status Solidi C. 2012. V. 9. P. 1462. https://doi.org/10.1002/pssc.201100677
Gordeeva E.O., Roslyakov I.V., Leontiev A.P. et al. // Beilstein J. Nanotechnology. 2021. V. 12. P. 957. 10.3762/bjnano.12.72' target='_blank'>https://doi.org/doi: 10.3762/bjnano.12.72
Ryzhkov I.I., Kharchenko I.A., Mikhlina E.V. et al. // Int. J. Heat Mass Transfer. 2021. V. 176. P. 121414. https://doi.org/10.1016/j.ijheatmasstransfer.2021.121414
Lee Y.H., Chang I., Cho G.Y. et al. // Int. J. Precision Engineering Manufacturing-Green Technology. 2018. V. 5. P. 441. https://doi.org/10.1007/s40684-018-0047-0
Roslyakov I.V., Kolesnik I.V., Evdokimov P.V. et al. // Sens. Actuators, B. 2021. V. 330. P. 129307. https://doi.org/10.1016/j.snb.2020.129307
Kalinin I.A., Roslyakov I.V., Tsymbarenko D.M. et al. // Sens. Actuators, A. 2021. V. 317. P. 112457. https://doi.org/10.1016/j.sna.2020.112457
Santos A. // J. Mater. Chem. C 2017. V. 5. P. 5581. https://doi.org/10.1039/C6TC05555A
Szwachta G., Bialek E., Wlodarski M. et al. // Nanotechnology. 2022. V. 33. P. 455707. https://doi.org/10.1088/1361-6528/ac83ca
Sadykov A.I., Kushnir S.E., Roslyakov I.V. et al. // Electrochem. Commun. 2019. V. 100. P. 104. https://doi.org/10.1016/j.elecom.2019.01.027
Roslyakov I.V., Gordeeva E.O., Napolskii K.S. // Electrochim. Acta. 2017. V. 241. P. 362. https://doi.org/10.1016/j.electacta.2017.04.140
Gordeeva E.O., Roslyakov I.V., Napolskii K.S. // Electrochim. Acta. 2019. V. 307. P. 13. https://doi.org/10.1016/j.electacta.2019.03.098
Petukhov D.I., Napolskii K.S., Berekchiyan M.V. et al. // ACS Appl. Mater. Interfaces. 2013. V. 5. P. 7819. https://doi.org/10.1021/am401585q
Noyan A.A., Leontiev A.P., Yakovlev M.V. et al. // Electrochim. Acta. 2017. V. 226. P. 60. https://doi.org/10.1016/j.electacta.2016.12.142
Masuda H., Hasegwa F., Ono S. // J. Electrochem. Soc. 1997. V. 144. P. L127. https://doi.org/10.1149/1.1837634
Masuda H., Fukuda K. // Science. 1995. V. 268. P. 1466. https://doi.org/10.1126/science.268.5216.1466
Nishinaga O., Kikuchi T., Natsui S. et al. // Sci. Rep. 2013. V. 3. P. 2748. https://doi.org/10.1038/srep02748
Akiya S., Kikuchi T., Natsui S. et al. // Electrochim. Acta. 2016. V. 190. P. 471. https://doi.org/10.1016/j.electacta.2015.12.162
Masuda H., Yada K., Osaka A. // Jpn. J. Appl. Phys. Lett. 1998. V. 37. P. L1340. https://doi.org/10.1143/JJAP.37.L1340
Almasi Kashi M., Ramazani A., Noormohammadi M. et al. // J. Phys. D: Appl. Phys. 2007. V. 40. P. 7032. https://doi.org/10.1088/0022-3727/40/22/025
Almasi Kashi M., Ramazani A., Mayamai Y. et al. // Jpn. J. Appl. Phys. 2010. V. 49. P. 015202–1. https://doi.org/10.1143/JJAP.49.015202
Xu Y.F., Liu H., Li X.J. et al. // Mater. Lett. 2015. V. 151. P. 79. https://doi.org/10.1016/j.matlet.2015.03.049
Mardilovich P.P., Govyadinoy A.N., Mazurenko N.I. et al. // J. Membr. Sci. 1995. V. 98. P. 143. https://doi.org/10.1016/0376-7388(94)00185-2
Ширин Н.А., Росляков И.В., Берекчиян М.В. и др. // Журн. неорган. химии. 2013. Т. 67. № 6. С. 868.
Lee Y.H., Ren H., Wu E.A. et al. // Nano Lett. 2020. V. 20. P. 2943. https://doi.org/10.1021/acs.nanolett.9b02344
Kousar R., Kim S.H., Byun J.Y. // J. King Saud University - Engineer. Sci. 2021.https://doi.org/10.1016/j.jksues.2021.09.003
Гордеева Е.О., Росляков И.В., Садыков А.И. и др. // Электрохимия. 2018. Т. 54. № 11. С. 999.
Schneider C.A., Rasband W.S., Eliceiri K.W. // Nat. Methods. 2012. V. 9. P. 671. https://doi.org/10.1038/nmeth.2089
Программы для анализа упорядочения пор в анодном оксиде алюминия. http://www.eng.fnm.msu.ru/software/
Lee W., Park S.J. // Chem. Rev. 2014. V. 114. P. 7487. https://doi.org/10.1021/cr500002z
Parkhutik V.P. // J. Phys. D: Appl. Phys. 1992. V. 25. P. 1258. https://doi.org/10.1088/0022-3727/25/8/017
Kim M., Kim H., Bae C. et al. // J. Phys. Chem. C. 2014. V. 118. P. 26789. https://doi.org/10.1021/jp507576c
Накамото К. ИК-спектры и спектры КР неорганических и координационных соединений / Пер. с англ. под ред. Пентина Ю.А. М.: Мир, 1991.
Vrublevsky I., Chernyakova K., Ispas A. et al. // J. Lumin. 2011. V. 131. P. 938. https://doi.org/10.1016/j.jlumin.2010.12.027
Mata-Zamora M.E., Saniger J.M. // Revista Mexicana de Fisica. 2005. V. 51. P. 502.
Roslyakov I.V., Kolesnik I.V., Levin E.E. et al. // Surf. Coat. Technol. 2020. V. 381. P. 125159. https://doi.org/10.1016/j.surfcoat.2019.125159
Roslyakov I.V., Shirin N.A., Berekchiian M.V. et al. // Microporous Mesoporous Mater. 2020. V. 294. P. 109840. https://doi.org/10.1016/j.micromeso.2019.109840
Lide D.R. CRC Handbook of Chemistry and Physics, 84th ed. CRC Press (2003).
Mardilovich P.P., Govyadinov A.N., Mukhurov N.I. et al. // J. Membr. Sci. 1995. V. 98. P. 131. https://doi.org/10.1016/0376-7388(94)00184-Z