Selective Sorbents Based on 2-Hydroxyethylmethacrylate and Ethylene Glycol Dimethacrylate Modified with Boric Acid as High-Affinity Ligands for Glucose

I. S. Garkushina; Гаркушина И. С.; A. S. Panyuta; Панюта А. С.; P. Yu. Morozova; Морозова П. Ю.; A. A. Osipenko; Осипенко А. А.

doi:10.31857/S0044185623700614

Selective Sorbents Based on 2-Hydroxyethylmethacrylate and Ethylene Glycol Dimethacrylate Modified with Boric Acid as High-Affinity Ligands for Glucose

Authors: Garkushina I.S.¹, Panyuta A.S.², Morozova P.Y.², Osipenko A.A.²
Affiliations:
1. Institute of Macromolecular Compounds, Russian Academy of SciencesInstitute of Macromolecular Compounds, Russian Academy of Sciences
2. Institute of Macromolecular Compounds, Russian Academy of Sciences
Issue: Vol 59, No 5 (2023)
Pages: 506-516
Section: ФИЗИКО-ХИМИЧЕСКИЕ ПРОЦЕССЫ НА МЕЖФАЗНЫХ ГРАНИЦАХ
URL: https://rjsvd.com/0044-1856/article/view/663928
DOI: https://doi.org/10.31857/S0044185623700614
EDN: https://elibrary.ru/VFENJM
ID: 663928

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Abstract

A synthesis method of granulated polymeric sorbents based on 2-hydroxyethylmethacrylate and ethylene glycol dimethacrylate that possess affinity to glucose sorption sites formed by boric acid molecules has been developed. The participation of boric acid as an additional crosslinking agent and the effect of the amount of the introduced ligand on the surface morphology of the granules and physicochemical properties of the polymeric sorbents have been determined. It has been found that this modification of the polymer matrix promotes an increase in the affinity of the sorption surface and its adsorption capacity to bind glucose in a dynamic mode, as well as high selectivity in comparison with the sorption of its structural analogue, fructose. This can further be used in the development of a method of isolation of glucose from a multicomponent solution and a sorption method of separation of sugars.

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