Sorbent based on manganese(III, IV) oxides of the MDM brand: preparation, sorption characteristics and application for purification of liquid radioactive waste from strontium and radium radionuclides

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The optimal conditions for the synthesis of a granular sorbent based on mixed Mn(III, IV) oxide by the interaction of aqueous solutions of MnSO4 and KMpO4 in an alkaline medium were determined: the molar ratio Mn2+/MnO4 is 1.70–1.80; the pH of the reaction mixture is 11.0–12.5; the calcination temperature is 220°C. For the sorbent obtained under optimal conditions, the values of the distribution coefficient (Kd) 90Sr in 0.01 M CaCl2 solution, the static exchange capacity for calcium, the hydromechanical strength of granules, as well as the dependence of Kd 90Sr on the concentration of sodium and calcium ions were determined. It is shown that the resulting sorbent has higher sorption characteristics with respect to strontium compared with known sorbents. A technology has been developed for the production of pilot batches of sorbent, named MDM. Examples of the use of MDM sorbent for the purification of various types of liquid radioactive waste from strontium and radium radionuclides are given.

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Sobre autores

V. Milyutin

Frumkin Institute of Physical Chemistry and Electrochemistry

Autor responsável pela correspondência
Email: vmilyutin@mail.ru
Rússia, Moscow, 119071

O. Kononenko

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: vmilyutin@mail.ru
Rússia, Moscow, 119071

N. Nekrasova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: vmilyutin@mail.ru
Rússia, Moscow, 119071

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2. Fig. 1. Derivatogram of a sample of mixed Mn(III, IV) oxide.

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3. Fig. 2. Dependence of Kd 90Sr on the concentration of sodium ions on sorbents: 1 – Mn(III, IV) oxide, 2 – Na-A zeolite, 3 – Tokem-100 sulfocationite.

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4. Fig. 3. Dependence of Kd 90Sr on the concentration of calcium ions on sorbents: 1 – Mn(III, IV) oxide, 2 – Tokem-100 sulfocationite, 3 – Na-A zeolite.

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