Localization of iodine and uranyl carbonate complex on metal-containing clay materials from aqueous media

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Abstract

The processes of localization of I2, I–, and [UO2(CO3)3]4– from aqueous solutions under static conditions on metal-containing clay powders from kaolin clays of the Kampanovskoye deposit and from bentonite clays of the 10th Khutor and Dinozavrovoe deposits were investigated. The studies were carried out with Cu-, Ni-, Zn-, and Fe-containing clay powders treated with a 2 mol/L solution of hydrazine hydrate. It was shown that the [UO2(CO3)3]4– complex is not sorbed on the synthesized clay materials from aqueous solutions under static conditions. It has been established that the synthesized clay materials are capable of not only reducing the amount of the molecular form of iodine in an aqueous solution, but also sorbing the ionic form of iodine from an aqueous solution of KI to almost 100% at a concentration of I– less than 10–2 mol/L.

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About the authors

E. P. Krasavina

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Moscow, 119071

K. V. Martynov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Moscow, 119071

K. G. Arzumanova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Moscow, 119071

A. V. Gordeev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Moscow, 119071

A. Y. Bomchuk

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Moscow, 119071

V. O. Zharkova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: kulyukhin@ipc.rssi.ru
Russian Federation, Moscow, 119071

S. A. Kulyukhin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Author for correspondence.
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Moscow, 119071

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2. Fig. 1. Initial and metal-containing clay materials after GG treatment. Arrangement of samples from left to right, 1st row from top: KGPO-23-GG, KGPO-23-Fe-GG, KGPO-23-Ni-GG, KGPO-28-GG; 2nd row from top: KhBGP-GG, KhBGP-Fe-GG, KhBGP-Cu-GG, DB-GG; 3rd row from top: DB-Fe-GG, DB-Ni-GG, DB-Cu-GG, DB-Zn-GG.

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3. Fig. 2. Initial and metal-containing clay KGPO-23 before and after GG treatment. 1 – KGPO-23-W, 2 – KGPO-23-GG, 3 – KGPO-23-Fe, 4 – KGPO-23-Fe-GG, 5 – KGPO-23-Ni, 6 – KGPO-23-Ni-GG; K – kaolinite [21], Q – quartz [22], D – diaspore Al2O3Ч.

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4. Fig. 3. Clay KGPO-28 before and after processing with GG. 1 – KGPO-28-W, 2 – KGPO-28-GG; K – kaolinite [21], Q – quartz [22], D – diaspore AlO(OH) [25], S – silicic acid [24], A – calcium aluminate Ca2Al2O5 [26].

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5. Fig. 4. Initial and metal-containing clay CBGP before and after treatment with GG. 1 – CBGP-W, 2 – CBGP-GG, 3 – CBGP-Fe, 4 – CBGP-Fe-GG, 5 – CBGP-Cu, 6 – CBGP-Cu-GG; Q – quartz [22], S – silicic acid HxSiyOz∙nH2O (x = 8, 2; y = 8, 14; z = 20, 29) [27, 28], A – calcium aluminate Ca3Al2O6 [29] (or Ca9Al6O18 [30]), Na-Mt – montmorillonite in the Na form [31], Ca-Mt – montmorillonite in the Ca form [32].

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6. Fig. 5. Initial and metal-containing clay DB before and after treatment with GG. 1 – DB-W, 2 – DB-GG, 3 – DB-Fe, 4 – DB-Fe-GG, 5 – DB-Ni, 6 – DB-Ni-GG, 7 – DB-Cu, 8 – DB-Cu-GG, 9 – DB-Zn, 10 – DB-Zn-GG; Ca-Mt – montmorillonite in the Ca-form [32], Q – quartz [22], S – silicic acid H2Si14O29∙ xH2O [28], A – calcium aluminate Ca3Al2O6 [29], A1 – calcium aluminate CaAl13.2O20.8 [33] (or CaAl2O4∙ 8.5H2O [34]), HA – calcium hydroxyaluminate aqueous Ca2Al(OH)7∙ 6.5H2O [35].

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