Nitration of Phenol with Water Activated by Pulsed Hot Plasma Radiation

I. M. Piskarev; Пискарев И. М.

doi:10.31857/S0023119323040113

Nitration of Phenol with Water Activated by Pulsed Hot Plasma Radiation

Authors: Piskarev I.M.¹
Affiliations:
1. Skobeltsyn Research Institute of Nuclear Physics, Moscow State University
Issue: Vol 57, No 4 (2023)
Pages: 336-340
Section: PLASMA CHEMISTRY
URL: https://rjsvd.com/0023-1193/article/view/661498
DOI: https://doi.org/10.31857/S0023119323040113
EDN: https://elibrary.ru/QOAAFV
ID: 661498

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Abstract

The nitration of phenol with plasma-activated water (PAW) generated by pulsed radiation of an electric spark discharge has been studied. Long-lived nitrogen-containing active species that accumulate in water during treatment are nitrous acid and the …ONOOH/ONOO− complex, which decomposes into peroxynitrite and peroxynitrous acid. Their concentration in PAW after 10 min of treatment was ~10−3 mol/L. When PAW is mixed with phenol in a 1 : 1 ratio, the identified reaction product is 4-nitrophenol. The yield
of nitration through PAW is equal to the nitration yield by the direct action of hot plasma radiation on a phenol solution.

Keywords

hot plasma radiation, nitration, phenol, plasma-activated water, 4-nitrophenol

About the authors

I. M. Piskarev

Skobeltsyn Research Institute of Nuclear Physics, Moscow State University

Author for correspondence.
Email: i.m.piskarev@gmail.com
Moscow, 119234 Russia

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