Email this article Nitration of Phenol with Water Activated by Pulsed Hot Plasma Radiation
- Authors: Piskarev I.M.1
-
Affiliations:
- Skobeltsyn Research Institute of Nuclear Physics, Moscow State University
- Issue: Vol 57, No 4 (2023)
- Pages: 336-340
- Section: PLASMA CHEMISTRY
- URL: https://rjsvd.com/0023-1193/article/view/661498
- DOI: https://doi.org/10.31857/S0023119323040113
- EDN: https://elibrary.ru/QOAAFV
- ID: 661498
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Abstract
The nitration of phenol with plasma-activated water (PAW) generated by pulsed radiation of an electric spark discharge has been studied. Long-lived nitrogen-containing active species that accumulate in water during treatment are nitrous acid and the …ONOOH/ONOO− complex, which decomposes into peroxynitrite and peroxynitrous acid. Their concentration in PAW after 10 min of treatment was ~10−3 mol/L. When PAW is mixed with phenol in a 1 : 1 ratio, the identified reaction product is 4-nitrophenol. The yield
of nitration through PAW is equal to the nitration yield by the direct action of hot plasma radiation on a phenol solution.
About the authors
I. M. Piskarev
Skobeltsyn Research Institute of Nuclear Physics, Moscow State University
Author for correspondence.
Email: i.m.piskarev@gmail.com
Moscow, 119234 Russia
References
- Zhou Renwu, Zhou Rusen, Wang P. et al. // Journal of Physics D: Applied Physics. 2020. V. 53. 303001.
- Balan G.G., Rosca I., Ursu E.-L. et al. // Infection and Drug Resistance. 2018. V. 11. P. 727.
- Vlad I.E., Martin C., Toth A.R. et al. // Romanian Reports in Physics. 2019. V. 71. Article 602.
- Mai-Prochnow A., Zhou Renwu, Zhang T. et al. // Biofilms and Microbiomes. 2021. V. 7. Article 11.
- Julak J., Hujacova A., Scholtz V. et al. // Plasma Physics Reports. 2018. V. 44. № 1. P. 125.
- Patel S.S., Patel D.B., Patel H.D. // ChemistrySelect. 2021. V. 6. P. 1.
- Hoggett G., Moodie R.B., Penton J.R., Schofield K. Nitration and aromatic reactivity. Cambridge University Press. 1971.
- Uppi R.M., Lemercier J.-N., Zhang H., Prior W.A. et al. // Archives of Biochemistry and Biophysics. 1998. V. 358. № 1. P. 1.
- Bowers G.N., McComb R.B., Christensen R.G., Schaffer R. // Clin. Chem. 1980. V. 26. № 6. P. 724.
- Amani K., Maleki F. // J. Iran. Chem. Soc. 2007. V. 4. № 2. P. 238.
- Pourali A.R., Goli A. // J. Chem. Sci. 2011. V. 123. № 1. P. 63.
- Patil M.R., Mohite P.H., Shisodia S., Keri S. // Letters in Organic Chemistry. 2015. V. 12. № 2. P. 129.
- Иванова И.П., Пискарев И.М. // Химия Высоких Энергий. 2022. Т. 56. № 5. С. 361. High Energy Chemistry. 2022. V. 56. № 5. P. 339.
- Пискарев И.М. // Химия Высоких Энергий. 2016. Т. 50. № 5. С. 449. High Energy Chemistry. 2016. V. 50. № 5. P. 71.
- Piskarev I.M., Ivanova I.P. // Plasma Chemistry and Plasma Processing. 2021. V. 41. № 1. P. 447.
- Piskarev I.M., Ivanova I.P. // Plasma Sources Sci. Technol. 2019. V. 28. 085008 P. 10.
- Пискарев И.М., Астафьева К.А., Иванова И.П. // Современные технологии в медицине. 2018. Т. 10. № 2. С. 90.
- Лобачев В.П., Рудаков Е.С. // Успехи химии. 2006. Т. 75. № 5. С. 422.
- Пискарев И.М. // Химия Высоких Энергий. 2018. Т. 52. № 4. С. 331. High Energy Chemistry. 2018. V. 52. № 4. P. 348.
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