Terephthalate and N-Oxide Isonicotinate Complexes of the {Mo6I8}4+ Cluster

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

The reaction of (TBA)2[Mo6I8(OAc)6] with terephthalic acid and isonicotinic acid N-oxide afforded new complexes, (TBA)2[Mo6I8(OOC-C6H4-COOH)6] (I) and (TBA)2[Mo6I8(OOC-C5H4NO)6] (II), respectively. The optimized synthesis of complex II involves microwave activation of the reaction mixture at 130°C in a Teflon reactor of the ETHOS UP Milestone microwave setup. According to X-ray diffraction data, the molybdenum atoms in the cluster cores of I and II are monodentately coordinated by carboxylate ligands. The cluster anions of complex I [Mo6I8(OOC-C6H4-COOH)6]2– are combined into a three-dimensional structure, the crystal structure contains solvate molecules. Samples of complexes I and II were characterized by elemental analysis for C, H, N, IR spectroscopy, electrospray mass spectrometry and proton magnetic resonance. For powder samples of I and II, bright phosphorescence with emission maxima at ~680 nm, φ = 15%, τ = 125 μs (I) and φ = 12%, τ = 137 μs (II) (in air at λExc = 440 nm) was revealed.

Авторлар туралы

M. Mikhaylov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: mikhajlovmaks@yandex.ru

T. Sukhikh

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: mikhajlovmaks@yandex.ru

D. Sheven

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: mikhajlovmaks@yandex.ru

E. Sadykov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: mikhajlovmaks@yandex.ru

M. Sokolov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia; Novosibirsk National Research State University, Novosibirsk, Russia

Email: mikhajlovmaks@yandex.ru

A. Berezin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: mikhajlovmaks@yandex.ru

K. Tagil’tsev

Novosibirsk National Research State University, Novosibirsk, Russia

Хат алмасуға жауапты Автор.
Email: mikhajlovmaks@yandex.ru

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