Symmetrical diynylic N-arylcarbamate molecules with different numbers of CH2 groups in spacers
- 作者: Alekseev A.S.1, Vyaz’min S.Y.2, Ivanov A.B.1, Klechkovskaya V.V.3, Lukasov M.S.3
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隶属关系:
- A.M. Prokhorov General Physics Institute of the Russian Academy of Science
- Zh.I. Alferov Federal State Budgetary Institution of Higher Education and Science St. Petersburg National Research Academic University of the Russian Academy of Science
- Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics of NRC “Kurchatov Institute”
- 期: 卷 69, 编号 5 (2024)
- 页面: 858-865
- 栏目: ПОВЕРХНОСТЬ, ТОНКИЕ ПЛЕНКИ
- URL: https://rjsvd.com/0023-4761/article/view/673740
- DOI: https://doi.org/10.31857/S0023476124050123
- EDN: https://elibrary.ru/ZCAFNQ
- ID: 673740
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详细
The photopolymerization of Langmuir-Schaefer films of diacetylene N-arylcarbamate symmetrical molecules containing different numbers of methylene groups in the molecules was studied. The result of diyne films UV irradiation was the effective transition of the films into the stable state of blue phase polydiacetylene. The number of CH2 groups in the molecules affected the efficiency of the monomers film transition into the polymer and the conjugation length of the polymer chains. Studying the morphology of the films using scanning electron microscopy showed the horizontal position of diyne molecules on the substrates in the state of domains, the sizes of which depended on the number of CH2 groups in the molecules.
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作者简介
A. Alekseev
A.M. Prokhorov General Physics Institute of the Russian Academy of Science
编辑信件的主要联系方式.
Email: alexanderalekseev@yandex.ru
俄罗斯联邦, Moscow
S. Vyaz’min
Zh.I. Alferov Federal State Budgetary Institution of Higher Education and Science St. Petersburg National Research Academic University of the Russian Academy of Science
Email: alexanderalekseev@yandex.ru
俄罗斯联邦, St. Petersburg
A. Ivanov
A.M. Prokhorov General Physics Institute of the Russian Academy of Science
Email: alexanderalekseev@yandex.ru
俄罗斯联邦, Moscow
V. Klechkovskaya
Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics of NRC “Kurchatov Institute”
Email: alexanderalekseev@yandex.ru
俄罗斯联邦, Moscow
M. Lukasov
Shubnikov Institute of Crystallography of Kurchatov Complex of Crystallography and Photonics of NRC “Kurchatov Institute”
Email: alexanderalekseev@yandex.ru
俄罗斯联邦, Moscow
参考
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